Structure and Properties of (C4N2H12)[Pt(NO3)6] Salt

被引：5

作者：

Vasilehenko, D. B. ^{[1
,2
]}

Topchiyan, P. A. ^{[1
,2
]}

Tkachev, S., V ^{[1
]}

Baidina, I. A. ^{[1
]}

Korolkov, I., V ^{[1
]}

Filatov, E. Yu ^{[1
,2
]}

Sheven, D. G. ^{[1
]}

机构：

[1] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk, Russia

[2] Novosibirsk State Univ, Novosibirsk, Russia

来源：

JOURNAL OF STRUCTURAL CHEMISTRY | 2019年 / 60卷 / 08期

基金：

俄罗斯科学基金会;

关键词：

platinum; nitrato complexes; piperazine; X-ray crystallographic analysis; MAS NMR; PT-195; NMR; CATALYST; STATE; NANOPARTICLES; PLATINUM(IV);

D O I：

10.1134/S0022476619080122

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

From a nitrate solution of platinum(IV) hydroxide, (C4N2H12)[Pt(N03)6] salt containing a piperazinium cation is isolated. The salt structure is determined by X-ray crystallography. Crystallographic data are: a=15.589(1)angstrom, b= 12.919(1) angstrom, c = 9.889(9)angstrom, beta = 08.625(4)degrees, space group C2/c, Z=4, rho(=)(calc) 2.306 g/cm(3). In the structure, [Pt(NO3)(6)](2-) anions having a shape of a trigonal antiprism are organized into a 3D network by the formation of hydrogen bonds with organic cations. For a series of salts containing [Pt(NO3)(6)](2-) and [Pt-2(omega-OH)(2)(NO3)(8)](2-) anionic platinum nitrato complexes a relationship between the structure and Pt-195 MAS NMR spectra is shown.

引用

页码：1327 / 1334

页数：8