Structure and Properties of (C4N2H12)[Pt(NO3)6] Salt

被引：5

作者：

Vasilehenko, D. B. ^{[1
,2
]}

Topchiyan, P. A. ^{[1
,2
]}

Tkachev, S., V ^{[1
]}

Baidina, I. A. ^{[1
]}

Korolkov, I., V ^{[1
]}

Filatov, E. Yu ^{[1
,2
]}

Sheven, D. G. ^{[1
]}

机构：

[1] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk, Russia

[2] Novosibirsk State Univ, Novosibirsk, Russia

来源：

JOURNAL OF STRUCTURAL CHEMISTRY | 2019年 / 60卷 / 08期

基金：

俄罗斯科学基金会;

关键词：

platinum; nitrato complexes; piperazine; X-ray crystallographic analysis; MAS NMR; PT-195; NMR; CATALYST; STATE; NANOPARTICLES; PLATINUM(IV);

D O I：

10.1134/S0022476619080122

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

From a nitrate solution of platinum(IV) hydroxide, (C4N2H12)[Pt(N03)6] salt containing a piperazinium cation is isolated. The salt structure is determined by X-ray crystallography. Crystallographic data are: a=15.589(1)angstrom, b= 12.919(1) angstrom, c = 9.889(9)angstrom, beta = 08.625(4)degrees, space group C2/c, Z=4, rho(=)(calc) 2.306 g/cm(3). In the structure, [Pt(NO3)(6)](2-) anions having a shape of a trigonal antiprism are organized into a 3D network by the formation of hydrogen bonds with organic cations. For a series of salts containing [Pt(NO3)(6)](2-) and [Pt-2(omega-OH)(2)(NO3)(8)](2-) anionic platinum nitrato complexes a relationship between the structure and Pt-195 MAS NMR spectra is shown.

引用

页码：1327 / 1334

页数：8

共 21 条

[1]

Bruker, 2001, SADABS

[2] Surface Engineering Protocol To Obtain an Atomically Dispersed Pt/CeO2 Catalyst with High Activity and Stability for CO OxidationD [J].

Chen, Jiayu ;

Wanyan, Yongjin ;

Zeng, Jianxin ;

Fang, Huihuang ;

Li, Zejun ;

Dong, Yongdi ;

Qin, Ruixuan ;

Wu, Changzheng ;

Liu, Deyu ;

Wang, Mingzhi ;

Kuang, Qin ;

Xie, Zhaoxiong ;

Zheng, Lansun .

ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2018, 6 (11) :14054-14062

[3] Characterization of PtIV-containing polyoxonietatates by high-resolution solid-state 195Pt and 51V NMR spectroscopy [J].

Dugar, Sneha ;

Izarova, Natalya V. ;

Mal, Sib Sankar ;

Fu, Riqiang ;

Joo, Hea-Chung ;

Lee, Uk ;

Dalal, Naresh S. ;

Pope, Michael T. ;

Jameson, Geoffrey B. ;

Kortz, Ulrich .

NEW JOURNAL OF CHEMISTRY, 2016, 40 (02) :923-927

[4] Tuning the Pt/CeO2 Interface by in Situ Variation of the Pt Particle Size [J].

Gaenzler, Andreas M. ;

Casapu, Maria ;

Maurer, Florian ;

Stoermer, Heike ;

Gerthsen, Dagmar ;

Ferre, Geraldine ;

Vernaux, Philippe ;

Bornmann, Benjamin ;

Frahm, Ronald ;

Murzin, Vadim ;

Nachtegaal, Maarten ;

Votsmeier, Martin ;

Grunwaldt, Jan-Dierk .

ACS CATALYSIS, 2018, 8 (06) :4800-4811

[5]

Gatla S, 2018, CATALYSIS TODAY

[6] Room-Temperature CO Oxidation Catalyst: Low-Temperature Metal-Support Interaction between Platinum Nanoparticles and Nanosized Ceria [J].

Gatla, Suresh ;

Aubert, Daniel ;

Agostini, Giovanni ;

Mathon, Olivier ;

Pascarelli, Sakura ;

Lunkenbein, Thomas ;

Willinger, Marc Georg ;

Kaper, Helena .

ACS CATALYSIS, 2016, 6 (09) :6151-6155

[7]

Kazuo N., 2009, Infrared and Raman Spectra of Inorganic and Coordination Compounds_ Part A_ Theory and Applications in Inorganic Chemistry, V6

[8] Modelling one- and two-dimensional solid-state NMR spectra [J].

Massiot, D ;

Fayon, F ;

Capron, M ;

King, I ;

Le Calvé, S ;

Alonso, B ;

Durand, JO ;

Bujoli, B ;

Gan, ZH ;

Hoatson, G .

MAGNETIC RESONANCE IN CHEMISTRY, 2002, 40 (01) :70-76

[9] Atomically Dispersed Pd, Ni, and Pt Species in Ceria-Based Catalysts: Principal Differences in Stability and Reactivity [J].

Neitzel, Armin ;

Figueroba, Alberto ;

Lykhach, Yaroslava ;

Skala, Tomas ;

Vorokhta, Mykhailo ;

Tsud, Nataliya ;

Mehl, Sascha ;

Sevcikova, Klara ;

Prince, Kevin C. ;

Neyman, Konstantin M. ;

Matolin, Vladimir ;

Libuda, Joerg .

JOURNAL OF PHYSICAL CHEMISTRY C, 2016, 120 (18) :9852-9862

[10] Activation of surface lattice oxygen in single-atom Pt/Ce02 for low-temperature CO oxidation [J].

Nie, Lei ;

Mei, Donghai ;

Xiong, Haifeng ;

Peng, Bo ;

Ren, Zhibo ;

Hernandez, Xavier Isidro Pereira ;

DeLariva, Andrew ;

Wang, Meng ;

Engelhard, Mark H. ;

Kovarik, Libor ;

Datye, Abhaya K. ;

Wang, Yong .

SCIENCE, 2017, 358 (6369) :1419-+

← 1 2 3 →