Species Uptake and Mass Transport in Membranes for Vanadium Redox Flow Batteries

被引：70

作者：

Elgammal, Ramez A. ^{[1
]}

Tang, Zhijiang ^{[1
,2
]}

Sun, Che-Nan ^{[2
]}

Lawton, Jamie ^{[1
]}

Zawodzinski, Thomas A., Jr. ^{[1
,2
]}

机构：

[1] Univ Tennessee, Dept Chem & Biomol Engn, Knoxville, TN 37996 USA

[2] Oak Ridge Natl Lab, Mat Sci & Technol Div, Oak Ridge, TN 37831 USA

来源：

ELECTROCHIMICA ACTA | 2017年 / 237卷

关键词：

PERFLUOROSULFONATED IONOMER MEMBRANES; PROTON-EXCHANGE MEMBRANES; SULFURIC-ACID-SOLUTIONS; WATER TRANSPORT; FUEL-CELL; IONIC-CONDUCTIVITY; NAFION MEMBRANES; PERFORMANCE; ELECTROLYTES; SEPARATOR;

D O I：

10.1016/j.electacta.2017.03.131

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

In this contribution, we provide a synthesis of results to date describing uptake and mass transport of water, vanadium species and protons in Nafion membranes for use as separators in VRFBs. Resistance issues as well as species cross-over are important contributors to performance loss in VRFBs. After a brief discussion of our state-of-the-art cell performance, we consider the uptake and transport of various species through a number of membrane materials. We draw together numerous previous studies and augment them with new data to provide a summary of our present state of understanding of the experimental facts regarding membrane behavior. (C) 2017 Published by Elsevier Ltd.

引用

页码：1 / 11

页数：11

共 58 条

[1] Dramatic performance gains in vanadium redox flow batteries through modified cell architecture [J].

Aaron, D. S. ;

Liu, Q. ;

Tang, Z. ;

Grim, G. M. ;

Papandrew, A. B. ;

Turhan, A. ;

Zawodzinski, T. A. ;

Mench, M. M. .

JOURNAL OF POWER SOURCES, 2012, 206 :450-453

[2] The Electronic Structure of the Vanadyl Ion [J].

Ballhausen, C. J. ;

Gray, Harry B. .

INORGANIC CHEMISTRY, 1962, 1 (01) :111-122

[3] Relationship between Steady-State Current in Symmetric Cells and Transference Number of Electrolytes Comprising Univalent and Multivalent Ions [J].

Balsara, Nitash P. ;

Newman, John .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2015, 162 (14) :A2720-A2722

[4] INFRARED SPECTROSCOPIC EVIDENCE FOR 2ND-SPHERE HYDRATION IN AQUEOUS-SOLUTIONS OF AL-3+, CR-3+, AND RH-3+ [J].

BERGSTROM, PA ;

LINDGREN, J ;

READ, M ;

SANDSTROM, M .

JOURNAL OF PHYSICAL CHEMISTRY, 1991, 95 (20) :7650-7655

[5] Determining the Limiting Current Density of Vanadium Redox Flow Batteries [J].

Chen, Jen-Yu ;

Hsieh, Chin-Lung ;

Hsu, Ning-Yih ;

Chou, Yi-Sin ;

Chen, Yong-Song .

ENERGIES, 2014, 7 (09) :5863-5873

[6] Absorption behavior of vanadium in Nafion® [J].

Cho, Hyun-Seok ;

Ohashi, Masato ;

Van Zee, J. W. .

JOURNAL OF POWER SOURCES, 2014, 267 :547-552

[7] Vanadium redox flow battery efficiency and durability studies of sulfonated Diels Alder poly(phenylene)s [J].

Fujimoto, Cy ;

Kim, Soowhan ;

Stains, Ronald ;

Wei, Xiaoliang ;

Li, Liyu ;

Yang, Zhenguo Gary .

ELECTROCHEMISTRY COMMUNICATIONS, 2012, 20 :48-51

[8] In Situ Potential Distribution Measurement and Validated Model for All-Vanadium Redox Flow Battery [J].

Gandomi, Yasser Ashraf ;

Aaron, D. S. ;

Zawodzinski, T. A. ;

Mench, M. M. .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2016, 163 (01) :A5188-A5201

[9] Concentrated Solution Model of Transport in All Vanadium Redox Flow Battery Membrane Separator [J].

Gandomi, Yasser Ashraf ;

Zawodzinski, T. A. ;

Mench, M. M. .

COMPUTATIONAL STUDIES ON BATTERY AND FUEL CELL MATERIALS, 2014, 61 (13) :23-32

[10] Water-mediated transport in ion-containing polymers [J].

Hickner, Michael A. .

JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 2012, 50 (01) :9-20

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