Zn(II) and Cd(II) N-carbazolylacetates with strong fluorescence

被引：45
作者：
Zhang, XJ
Tian, YP [1 ]
Li, SL
Jiang, MH
Usman, A
Chantrapromma, S
Fun, HK
机构：
[1] Anhui Univ, Dept Chem, Hefei 230039, Peoples R China
[2] Shandong Univ, State Key Lab Crystal Mat, Jinan 250100, Peoples R China
[3] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China
[4] Univ Sains Malaysia, Sch Phys, Xray Crystallog Unit, George Town 11800, Malaysia
来源：
POLYHEDRON | 2003年 / 22卷 / 03期
基金：
中国国家自然科学基金;
关键词：
carbazole; N-carbazolylacetate; crystal structures; complexes; photoluminescence;
D O I：
10.1016/S0277-5387(02)01360-8
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
N-carbazolylacetic acid was synthesized using a new method in a high yield and two carbazolylacetato complexes [Zn(Cabo)(phen)(2)ClO4].0.5C(2)H(5)OH and [Cd(Cabo)(phen)(2)-ClO4] (Cabo = N-carbazolylacetate, phen = 1,10-phenanthroline) were synthesized and characterized by elemental analysis, IR, UV-Vis spectra, thermal analyses, photoluminescence measurement and X-ray diffraction studies. Both of the complexes exhibit strong blue emission in solid state as well as high thermal stability and solvent-resistant properties. (C) 2002 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：397 / 402
页数：6
相关论文
共 25 条
[1]   Chiral stilbazolium chromophores: An approach toward multiproperty materials combining conductivity and second-order optical nonlinearities [J].
Andreu, R ;
Malfant, I ;
Lacroix, PG ;
Gornitzka, H ;
Nakatani, K .
CHEMISTRY OF MATERIALS, 1999, 11 (03) :840-848
[2]  
BRUCK P, 1970, J CHEM SOC B, V13, P205
[3]   1-DIMENSIONAL, 2-DIMENSIONAL, AND 3-DIMENSIONAL POLYMERIC FRAMES IN THE COORDINATION CHEMISTRY OF AGBF4 WITH PYRAZINE - THE FIRST EXAMPLE OF 3 INTERPENETRATING 3-DIMENSIONAL TRICONNECTED NETS [J].
CARLUCCI, L ;
CIANI, G ;
PROSERPIO, DM ;
SIRONI, A .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (16) :4562-4569
[4]   A photorefractive organically modified silica glass with high optical gain [J].
Cheben, P ;
del Monte, F ;
Worsfold, DJ ;
Carlsson, DJ ;
Grover, CP ;
Mackenzie, JD .
NATURE, 2000, 408 (6808) :64-67
[5]   PHOTOCHEMICAL AND PHOTOPHYSICAL PROPERTIES OF TETRANUCLEAR AND HEXANUCLEAR CLUSTERS OF METALS WITH D10 AND S2 ELECTRONIC CONFIGURATIONS [J].
FORD, PC ;
VOGLER, A .
ACCOUNTS OF CHEMICAL RESEARCH, 1993, 26 (04) :220-226
[6]   The first structurally characterized 3,4′-bipyridine copper(I) coordination polymer with an approximately rectangular molecular box [J].
Fun, HK ;
Raj, SSS ;
Xiong, RG ;
Zuo, JL ;
Yu, Z ;
Zhu, XL ;
You, XZ .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1999, (11) :1711-1712
[7]   ON PHOTOELECTRIC EFFECTS IN POLYMERS AND THEIR SENSITIZATION BY DOPANTS [J].
HOEGL, H .
JOURNAL OF PHYSICAL CHEMISTRY, 1965, 69 (03) :755-&
[8]   POLY(N-ACYLETHYLENIMINES) WITH PENDANT CARBAZOLE DERIVATIVES .2. SYNTHESIS OF 3,6-DIMETHOXYCARBAZOLE-CONTAINING, 3,6-DIHYDROXYCARBAZOLE-CONTAINING, AND 2,7-DIHYDROXYCARBAZOLE-CONTAINING POLYMERS [J].
HSIEH, BR ;
LITT, MH .
MACROMOLECULES, 1986, 19 (03) :516-520
[9]   THE NATURE OF PI-PI INTERACTIONS [J].
HUNTER, CA ;
SANDERS, JKM .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (14) :5525-5534
[10]   SYNTHESIS, ELECTROCHEMICAL CHARACTERIZATION, AND ASSEMBLY INTO LANGMUIR-BLODGETT-FILMS OF SOME N-SUBSTITUTED DERIVATIVES OF POLY(3,6-CARBAZOLYLMETHYLENE) [J].
LOWEN, SV ;
BUSCHEK, J ;
MASTANTUONO, R ;
HOLDEN, DA ;
KOVACS, GJ ;
LOUTFY, RO .
MACROMOLECULES, 1990, 23 (13) :3242-3249
123