Relationship between vibrations and dynamical heterogeneity in a model glass former: Extended soft modes but local relaxation

被引:23
作者
Ashton, D. J. [1 ,2 ]
Garrahan, J. P. [1 ]
机构
[1] Univ Nottingham, Sch Phys & Astron, Nottingham NG7 2RD, England
[2] Univ Bath, Dept Phys, Bath BA2 7AY, Avon, England
基金
英国工程与自然科学研究理事会;
关键词
FORCE ELASTIC NETWORKS; LATTICE-GAS MODEL; SUPERCOOLED LIQUIDS; AMORPHOUS SOLIDS; PERCOLATION; TRANSITION;
D O I
10.1140/epje/i2009-10531-6
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We study the relation between short-time vibrational modes and long-time relaxational dynamics in a kinetically constrained lattice gas with harmonic interactions between neighbouring particles. We find a correlation between the location of the low- (high-) frequency vibrational modes and regions of high (low) propensity for motion. This is similar to what was observed in continuous force systems, but our interpretation is different: in our case relaxation is due to localised excitations which propagate through the system; these localised excitations act as background disorder for the elastic network, giving rise to anomalous vibrational modes. Our results provide an example whereby a correlation between spatially extended low-frequency modes and high-propensity regions does not imply that relaxational dynamics originates in extended soft modes but rather belies their common origin. We consider other measures of elastic heterogeneity, such as non-affine displacement fields and mode localisation lengths, and discuss implications of our results to interpretations of dynamic heterogeneity more generally.
引用
收藏
页码:303 / 307
页数:5
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