Statistical radical copolymerization of styrene and methyl methacrylate in a room temperature ionic liquid

被引：50

作者：

Zhang, HW

Hong, KL

Jablonsky, M

Mays, JW ^{[1
]}

机构：

[1] Oak Ridge Natl Lab, Div Chem Sci, Oak Ridge, TN 37831 USA

[2] Univ Tennessee, Dept Mat Sci & Engn, Knoxville, TN 37996 USA

[3] Univ Tennessee, Dept Chem, Knoxville, TN 37996 USA

[4] Univ Alabama Birmingham, Dept Chem, Birmingham, AL 35294 USA

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 12期

关键词：

D O I：

10.1039/b301562a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Use of a room temperature ionic liquid as the medium for conventional free radical copolymerization of styrene and methyl methacrylate resulted in reactivity ratios that were significantly different from those obtained in conventional organic solvents or in bulk, demonstrating that polymerization in this alternative medium offers potential to create copolymers having new monomer sequences.

引用

页码：1356 / 1357

页数：2

共 30 条

[1] Atom transfer radical polymerization of acrylates in an ionic liquid: Synthesis of block copolymers [J].