Recent Progress in Decarboxylative Oxidative Cross-Coupling for Biaryl Synthesis

被引：120

作者：

Perry, Gregory J. P. ^{[1
]}

Larrosa, Igor ^{[1
]}

机构：

[1] Univ Manchester, Sch Chem, Oxford Rd, Manchester M13 9PL, Lancs, England

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2017年 / 2017卷 / 25期

基金：

英国工程与自然科学研究理事会;

关键词：

Decarboxylation; C-H activation; Cross-coupling; Biaryls; Oxidative Coupling; AROMATIC CARBOXYLIC-ACIDS; COPPER-CATALYZED DECARBOXYLATION; SUBSTITUTED BENZOIC-ACIDS; ARYL BOND FORMATION; C-H ARYLATION; GOLD(I)-CATALYZED PROTODECARBOXYLATION; ARENECARBOXYLIC ACIDS; 2-NITROBENZOIC ACIDS; CUPROUS CARBOXYLATES; ACTIVATION;

D O I：

10.1002/ejoc.201700121

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The beginning of the 21st century has seen tremendous growth in the field of decarboxylative activation. Benzoic acid derivatives are now recognised as atom-economic alternatives to traditional cross-coupling partners, and they also benefit from being inexpensive, readily available and shelf-stable reagents. In this microreview we discuss recent developments in the coupling of benzoic acid derivatives either with an arene or with a second benzoic acid derivative, a process often termed decarboxylative oxidative cross-coupling. These procedures offer great promise for the development of highly selective and atom-economic cross-couplings.

引用

页码：3517 / 3527

页数：11