Synthesis, structures, and properties of a series of similar structural coordination polymers with triphosphonate anions as ligands

被引：10

作者：

Guan, Lei ^{[1
]}

Wang, Ying ^{[1
]}

机构：

[1] Liaoning Univ Petr & Chem Engn, Coll Chem Chem Engn & Environm Engn, Fushun, Peoples R China

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2017年 / 70卷 / 14期

关键词：

Triphosphonate anion; coordination polymer; magnetic property; METAL-ORGANIC FRAMEWORKS; SCHIFF-BASE COMPLEXES; MAGNETIC-PROPERTIES; PHOTOPHYSICAL PROPERTIES; PHOSPHONATE FRAMEWORKS; HYDROTHERMAL SYNTHESIS; COPPER PHOSPHONATES; CRYSTAL-STRUCTURE; BUILDING-BLOCKS; CATION-EXCHANGE;

D O I：

10.1080/00958972.2017.1354249

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The hydrothermal reactions of metal precursors with aminotri(methylenephosphonic acid) yielded a series of similar structural coordination polymers of general formula {M[HN(CH2PO3H)(3)](H2O)(3)}(n) [M = Mg(II) (1), Mn(II) (2), Co(II) (3), Zn(II) (4) and Cd(II) (5)]. Compounds 1-5 were characterized by X-ray single crystal diffraction, elemental analyses, and thermogravimetric analyses. Compounds 1-5 all reveal the wave-like 1D chain structures and the structures are constructed by two types of eight-membered, square-like rings linked alternatively via the phosphonate oxygen atoms, generating double-channel systems. The magnetic studies of 2 and 3 reveal that antiferromagnetic interactions are mediated between the metal ions.

引用

页码：2530 / 2540

页数：11

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