Thermal conductivity reduction in fullerene-enriched p-type bismuth telluride composites

被引:20
作者
Gothard, N. [1 ,2 ]
Spowart, J. E. [2 ]
Tritt, T. M. [1 ]
机构
[1] Clemson Univ, Dept Phys & Astron, Clemson, SC 29634 USA
[2] USAF, Res Lab, Mat & Mfg Directorate, Wright Patterson AFB, OH 45433 USA
来源
PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE | 2010年 / 207卷 / 01期
关键词
THERMOELECTRIC-MATERIALS; FIGURE; SCATTERING; APPARATUS;
D O I
10.1002/pssa.200925145
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We present a systematic study of the effects of fullerene nanoinclusions upon a p-type bismuthy-antimony-telluride matrix where the ultimate goal is maximizing the figure of merit by reducing the thermal conductivity (TC) Nanocomposites consisting of a bismuth-telluride matrix with fullerene inclusions have been prepared both by mechanical mixing and ball milling, with the final consolidation in each case achieved by uniaxial hot pressing. A series of samples was produced with fullerene concentrations ranging from fractional levels to several molar percent, and the effects of the fullerence additions upon the resulting. microstructure have been considered. Thermal and electrical, transport properties have been measured from 10 to 300 K, and the data are discussed in light of the underlying physical mechanisms.
引用
收藏
页码:157 / 162
页数:6
相关论文
共 25 条
[1]   Thermoelectric properties of La0.9CoFe3Sb12-CoSb3 skutterudite nanocomposites [J].
Alboni, P. N. ;
Ji, X. ;
He, J. ;
Gothard, N. ;
Tritt, Terry M. .
JOURNAL OF APPLIED PHYSICS, 2008, 103 (11)
[2]   Fullerite additions as a phonon scattering mechanism in p-type Si-20 at.% Ge [J].
Cook, BA ;
Harringa, JL ;
Loughin, S .
MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY, 1996, 41 (02) :280-288
[3]  
Dresselhaus M S, 2005, MATER RES SOC S P, V886
[4]   Thermoelectric and transport properties of n-type Bi2Te3 nanocomposites [J].
Gothard, N. ;
Ji, X. ;
He, J. ;
Tritta, Terry M. .
JOURNAL OF APPLIED PHYSICS, 2008, 103 (05)
[5]   Quantum dot superlattice thermoelectric materials and devices [J].
Harman, TC ;
Taylor, PJ ;
Walsh, MP ;
LaForge, BE .
SCIENCE, 2002, 297 (5590) :2229-2232
[6]   EFFECT OF QUANTUM-WELL STRUCTURES ON THE THERMOELECTRIC FIGURE OF MERIT [J].
HICKS, LD ;
DRESSELHAUS, MS .
PHYSICAL REVIEW B, 1993, 47 (19) :12727-12731
[7]   Cubic AgPbmSbTe2+m:: Bulk thermoelectric materials with high figure of merit [J].
Hsu, KF ;
Loo, S ;
Guo, F ;
Chen, W ;
Dyck, JS ;
Uher, C ;
Hogan, T ;
Polychroniadis, EK ;
Kanatzidis, MG .
SCIENCE, 2004, 303 (5659) :818-821
[8]  
Landolt H. H., 1983, NUMERICAL DATA FUNCT, P272
[9]   PbTe nanocomposites synthesized from PbTe nanocrystals [J].
Martin, J. ;
Nolas, G. S. ;
Zhang, W. ;
Chen, L. .
APPLIED PHYSICS LETTERS, 2007, 90 (22)
[10]   THE HALL-EFFECT IN POLYCRYSTALLINE AND POWDERED SEMICONDUCTORS [J].
ORTON, JW ;
POWELL, MJ .
REPORTS ON PROGRESS IN PHYSICS, 1980, 43 (11) :1263-1307