Nanoflower shaped NiO/CeO2 p-n junction material for the degradation of pollutant under visible light

被引:2
作者
Gnanasekaran, Lalitha [1 ]
Jalil, A. A. [2 ,3 ]
Kumar, Senthil [4 ]
Rajendran, Saravanan [1 ]
Gracia, F. [5 ]
Soto-Moscoso, Matias [6 ]
Habila, Mohamed A. [7 ]
Saravanakumar, Karunamoorthy [8 ]
机构
[1] Univ Tarapaca, Fac Ingn, Dept Ingn Mecan, Avda Gen Velasquez 1775, Arica, Chile
[2] Univ Teknol Malaysia, Fac Engn, Sch Chem & Energy Engn, Utm Johor Bahru 81310, Johor, Malaysia
[3] Inst Future Energy, Ctr Hydrogen Energy, Utm Johor Bahru 81310, Johor, Malaysia
[4] Sri Sivasubramaniya Nadar Coll Engn, Dept Chem Engn, Chennai 603110, Tamil Nadu, India
[5] Univ Chile, Dept Chem Engn Biotechnol & Mat, Beauchef 851,6th Floor, Santiago, Chile
[6] Univ Bio Bio, Fac Ciencias, Dept Fis, Ave Collao 1202,Casilla 15-C, Concepcion, Chile
[7] King Saud Univ, Coll Sci, Dept Chem, POB 2455, Riyadh 11451, Saudi Arabia
[8] Kyungpook Natl Univ, Dept Environm Engn, 80 Daehak Ro, Daegu 41566, South Korea
关键词
Photocatalyst; Semiconductor; p-n Junctions; Methyl orange; Oxidation;
D O I
10.1016/j.matlet.2022.132122
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The potential need of p-n junctions create an optimistic way of supporting photogenerated electron-hole pair separation and improving interfacial charge-transfer rates. In this context, a p-type semiconductor NiO can couple with n-type CeO2, thus approving visible light activity by forming p-n junctions. The visible light activity of two large band gap semiconductors still lacks some significant reasons. To solve this, for the first time, this paper reports 3D flower shaped p n heterojunction NiO/CeO2 synthesized via thermal decomposition method and studied their properties through various instrumental techniques. Besides, the photocatalytic mechanism of p n junction and the degrading efficiency of organic pollutant methyl orange (MO) for the synthesized catalysts was discussed. This achieves the outstanding activity and showed better stability which are useful for future applications.
引用
收藏
页数:4
相关论文
共 13 条
  • [1] Ahmed D.N., 2020, SCI REP-UK, V2042, P2666
  • [2] Preparation of ZnO Photocatalyst for the Efficient and Rapid Photocatalytic Degradation of Azo Dyes
    Chen, Xiaoqing
    Wu, Zhansheng
    Liu, Dandan
    Gao, Zhenzhen
    [J]. NANOSCALE RESEARCH LETTERS, 2017, 12
  • [3] ELECTROCHEMICAL PHOTOLYSIS OF WATER AT A SEMICONDUCTOR ELECTRODE
    FUJISHIMA, A
    HONDA, K
    [J]. NATURE, 1972, 238 (5358) : 37 - +
  • [4] NiO decorated CeO2 nanostructures as room temperature isopropanol gas sensors
    Jayababu, Nagabandi
    Poloju, Madhukar
    Shruthi, Julakanti
    Reddy, M. V. Ramana
    [J]. RSC ADVANCES, 2019, 9 (24) : 13765 - 13775
  • [5] Tuning of metal oxides photocatalytic performance using Ag nanoparticles integration
    Karimi-Maleh, Hassan
    Kumar, Baskaran Ganesh
    Rajendran, Saravanan
    Qin, Jiaqian
    Vadivel, S.
    Durgalakshmi, D.
    Gracia, F.
    Soto-Moscoso, Matias
    Orooji, Yasin
    Karimi, Fatemeh
    [J]. JOURNAL OF MOLECULAR LIQUIDS, 2020, 314
  • [6] MOF-derived NiO/CeO2heterojunction: a photocatalyst for degrading pollutants and hydrogen evolution
    Li, Pengfei
    Zhang, Ming
    Li, Xuewei
    Wang, Chao
    Wang, Ruzhi
    Wang, Bo
    Yan, Hui
    [J]. JOURNAL OF MATERIALS SCIENCE, 2020, 55 (33) : 15930 - 15944
  • [7] Photodegradation of toxic dye using Gum Arabic-crosslinked-poly(acrylamide)/Ni(OH)2/FeOOH nanocomposites hydrogel
    Naushad, Mu.
    Sharma, Gaurav
    Alothman, Zeid A.
    [J]. JOURNAL OF CLEANER PRODUCTION, 2019, 241
  • [8] Heterogeneous UV-Switchable Au nanoparticles decorated tungstophosphoric acid/TiO2 for efficient photocatalytic degradation process
    Orooji, Yasin
    Tanhaei, Bahareh
    Ayati, Ali
    Tabrizi, Soheil Hamidi
    Alizadeh, Marzieh
    Bamoharram, Fatemeh F.
    Karimi, Fatemeh
    Salmanpour, Sadegh
    Rouhi, Jalal
    Afshar, Safoora
    Sillanpaa, Mika
    Darabi, Rozhin
    Karimi-Maleh, Hassan
    [J]. CHEMOSPHERE, 2021, 281
  • [9] Influence of mesoporous defect induced mixed-valent NiO (Ni2+/Ni3+)-TiO2 nanocomposite for non-enzymatic glucose biosensors
    Rajendran, Saravanan
    Manoj, Devaraj
    Raju, Kumar
    Dionysiou, Dionysios D.
    Naushad, Mu
    Gracia, F.
    Cornejo, Lorena
    Gracia-Pinilla, M. A.
    Ahamad, Tansir
    [J]. SENSORS AND ACTUATORS B-CHEMICAL, 2018, 264 : 27 - 37
  • [10] ZnO/CdO composite nanorods for photocatalytic degradation of methylene blue under visible light
    Saravanan, R.
    Shankar, H.
    Prakash, T.
    Narayanan, V.
    Stephen, A.
    [J]. MATERIALS CHEMISTRY AND PHYSICS, 2011, 125 (1-2) : 277 - 280