Facile fabrication of Bi2S3/SnS2 heterojunction photocatalysts with efficient photocatalytic activity under visible light

被引:90
作者
Gao, Xiaomin [1 ]
Huang, Guanbo [1 ]
Gao, Haihuan [2 ]
Pan, Cheng [1 ]
Wang, Huan [1 ]
Yan, Jing [1 ,3 ]
Liu, Yu [1 ]
Qiu, Haixia [1 ,3 ]
Ma, Ning [1 ]
Gao, Jianping [1 ,3 ]
机构
[1] Tianjin Univ, Sch Sci, Dept Chem, Tianjin 300072, Peoples R China
[2] Tianjin Fourth Middle Sch, Tianjin 300021, Peoples R China
[3] Collaborat Innovat Ctr Chem Sci & Engn, Tianjin 300072, Peoples R China
基金
美国国家科学基金会;
关键词
Photocatalysts; Bi2S3/SnS2; heterojunctions; Degradation; Methyl orange; Visible light; HEXAGONAL SNS2 NANOSHEETS; ION-EXCHANGE SYNTHESIS; HIGH-PERFORMANCE; TIN DISULFIDE; SOLVOTHERMAL SYNTHESIS; AZO-DYE; NANOCOMPOSITES; SEMICONDUCTOR; OXIDATION; REDUCTION;
D O I
10.1016/j.jallcom.2016.03.031
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this work, Bi2S3/SnS2 heterojunction photocatalysts were prepared by combining a hydrothermal technique and a facile in situ growth method. The nanocomposites were characterized by X-ray diffraction, scanning electron microscopy, transmission electron microscopy, inductively coupled plasma spectroscopy, X-ray photoelectron spectroscopy, UVeVis diffusion reflectance spectroscopy and room-temperature photoluminescence spectra. Their photocatalytic performances were evaluated by degrading methyl orange (MO) in aqueous solution (50 mg/L) under visible light (lambda > 420 nm) irradiation. It was found that when the mass percentage of Bi2S3 in Bi2S3/SnS2 was 7.95 wt%, the as-prepared Bi2S3/SnS2 nanocomposite showed the best photocatalytic activity for the degradation of MO. The highly improved performance of the Bi2S3/SnS2 nanocomposite was mainly ascribed to the efficient charge separation. (C) 2016 Elsevier B. V. All rights reserved.
引用
收藏
页码:98 / 108
页数:11
相关论文
共 59 条
[51]   Size-Tunable Hydrothermal Synthesis of SnS2 Nanocrystals with High Performance in Visible Light-Driven Photocatalytic Reduction of Aqueous Cr(VI) [J].
Zhang, Yong Cai ;
Li, Jing ;
Zhang, Ming ;
Dionysiou, Dionysios D. .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2011, 45 (21) :9324-9331
[52]   High-Performance Visible-Light-Driven SnS2/SnO2 Nanocomposite Photocatalyst Prepared via In situ Hydrothermal Oxidation of SnS2 Nanoparticles [J].
Zhang, Yong Cai ;
Du, Zhen Ni ;
Li, Kun Wei ;
Zhang, Ming ;
Dionysiou, Dionysios D. .
ACS APPLIED MATERIALS & INTERFACES, 2011, 3 (05) :1528-1537
[53]   Novel synthesis and high visible light photocatalytic activity of SnS2 nanoflakes from SnCl2•2H2O and S powders [J].
Zhang, Yong Cai ;
Du, Zhen Ni ;
Li, Shi Yin ;
Zhang, Ming .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2010, 95 (1-2) :153-159
[54]   Ultrathin hexagonal SnS2 nanosheets coupled with g-C3N4 nanosheets as 2D/2D heterojunction photocatalysts toward high photocatalytic activity [J].
Zhang, Zhenyi ;
Huang, Jindou ;
Zhang, Mingyi ;
Yuan, Ling ;
Dong, Bin .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2015, 163 :298-305
[55]   Hierarchical assembly of ultrathin hexagonal SnS2 nanosheets onto electrospun TiO2 nanofibers: enhanced photocatalytic activity based on photoinduced interfacial charge transfer [J].
Zhang, Zhenyi ;
Shao, Changlu ;
Li, Xinghua ;
Sun, Yangyang ;
Zhang, Mingyi ;
Mu, Jingbo ;
Zhang, Peng ;
Guo, Zengcai ;
Liu, Yichun .
NANOSCALE, 2013, 5 (02) :606-618
[56]   Enhancement of Visible-Light Photocatalysis by Coupling with Narrow-Band-Gap Semiconductor: A Case Study on Bi2S3/Bi2WO6 [J].
Zhang, Zhijie ;
Wang, Wenzhong ;
Wang, Lu ;
Sun, Songmei .
ACS APPLIED MATERIALS & INTERFACES, 2012, 4 (02) :593-597
[57]   Vertically Aligned Graphene-Like SnS2 Ultrathin Nanosheet Arrays: Excellent Energy Storage, Catalysis, Photoconduction, and Field-Emitting Performances [J].
Zhong, Haoxiang ;
Yang, Gongzheng ;
Song, Huawei ;
Liao, Qingyu ;
Cui, Hao ;
Shen, Peikang ;
Wang, Cheng-Xin .
JOURNAL OF PHYSICAL CHEMISTRY C, 2012, 116 (16) :9319-9326
[58]   Synthesis of g-C3N4/Ag3VO4 composites with enhanced photocatalytic activity under visible light irradiation [J].
Zhu, Tingting ;
Song, Yanhua ;
Ji, Haiyan ;
Xu, Yuanguo ;
Song, Yongxiu ;
Xia, Jiexiang ;
Yin, Sheng ;
Li, Yeping ;
Xu, Hui ;
Zhang, Qi ;
Li, Huaming .
CHEMICAL ENGINEERING JOURNAL, 2015, 271 :96-105
[59]   Ultrasonic-assisted synthesis of amorphous Bi2S3 coupled (BiO)2CO3 catalyst with improved visible light-responsive photocatalytic activity [J].
Zhu, Yingming ;
Xu, Dandan ;
Meng, Ming .
JOURNAL OF MATERIALS SCIENCE, 2015, 50 (04) :1594-1604