Facile fabrication of Bi2S3/SnS2 heterojunction photocatalysts with efficient photocatalytic activity under visible light

被引:90
作者
Gao, Xiaomin [1 ]
Huang, Guanbo [1 ]
Gao, Haihuan [2 ]
Pan, Cheng [1 ]
Wang, Huan [1 ]
Yan, Jing [1 ,3 ]
Liu, Yu [1 ]
Qiu, Haixia [1 ,3 ]
Ma, Ning [1 ]
Gao, Jianping [1 ,3 ]
机构
[1] Tianjin Univ, Sch Sci, Dept Chem, Tianjin 300072, Peoples R China
[2] Tianjin Fourth Middle Sch, Tianjin 300021, Peoples R China
[3] Collaborat Innovat Ctr Chem Sci & Engn, Tianjin 300072, Peoples R China
基金
美国国家科学基金会;
关键词
Photocatalysts; Bi2S3/SnS2; heterojunctions; Degradation; Methyl orange; Visible light; HEXAGONAL SNS2 NANOSHEETS; ION-EXCHANGE SYNTHESIS; HIGH-PERFORMANCE; TIN DISULFIDE; SOLVOTHERMAL SYNTHESIS; AZO-DYE; NANOCOMPOSITES; SEMICONDUCTOR; OXIDATION; REDUCTION;
D O I
10.1016/j.jallcom.2016.03.031
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this work, Bi2S3/SnS2 heterojunction photocatalysts were prepared by combining a hydrothermal technique and a facile in situ growth method. The nanocomposites were characterized by X-ray diffraction, scanning electron microscopy, transmission electron microscopy, inductively coupled plasma spectroscopy, X-ray photoelectron spectroscopy, UVeVis diffusion reflectance spectroscopy and room-temperature photoluminescence spectra. Their photocatalytic performances were evaluated by degrading methyl orange (MO) in aqueous solution (50 mg/L) under visible light (lambda > 420 nm) irradiation. It was found that when the mass percentage of Bi2S3 in Bi2S3/SnS2 was 7.95 wt%, the as-prepared Bi2S3/SnS2 nanocomposite showed the best photocatalytic activity for the degradation of MO. The highly improved performance of the Bi2S3/SnS2 nanocomposite was mainly ascribed to the efficient charge separation. (C) 2016 Elsevier B. V. All rights reserved.
引用
收藏
页码:98 / 108
页数:11
相关论文
共 59 条
[41]   Effect of Ordered TiO2 Nanotube Array Substrate on Photocatalytic Performance of CdS-Sensitized ZnO Nanorod Arrays [J].
Wu, Liangpeng ;
Li, Juan ;
Zhang, Shaohong ;
Long, Lizhen ;
Li, Xinjun ;
Cen, Chaoping .
JOURNAL OF PHYSICAL CHEMISTRY C, 2013, 117 (44) :22591-22597
[42]   Controlled synthesis of Bi2S3/ZnS microspheres by an in situ ion-exchange process with enhanced visible light photocatalytic activity [J].
Wu, Zhudong ;
Chen, Linlin ;
Xing, Chaosheng ;
Jiang, Deli ;
Xie, Jimin ;
Chen, Min .
DALTON TRANSACTIONS, 2013, 42 (36) :12980-12988
[43]   Facile ion-exchange synthesis of mesoporous Bi2S3/ZnS nanoplate with high adsorption capability and photocatalytic activity [J].
Xiong, Dan-Ni ;
Huang, Gui-Fang ;
Zhou, Bing-Xin ;
Yan, Qian ;
Pan, An-Lian ;
Huang, Wei-Qing .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2016, 464 :103-109
[44]   Hollow ZnFe2O4/TiO2 composites: High-performance and recyclable visible-light photocatalyst [J].
Xu, Qingqing ;
Feng, Jiantao ;
Li, Liangchao ;
Xiao, Qiushi ;
Wang, Jun .
JOURNAL OF ALLOYS AND COMPOUNDS, 2015, 641 :110-118
[45]   Novel heterostructured Bi2S3/Bi2Sn2O7 with highly visible light photocatalytic activity for the removal of rhodamine B [J].
Xu, Weicheng ;
Fang, Jianzhang ;
Chen, Yunfang ;
Lu, Shaoyou ;
Zhou, Guangying ;
Zhu, Ximiao ;
Fang, Zhanqiang .
MATERIALS CHEMISTRY AND PHYSICS, 2015, 154 :30-37
[46]   CdS/g-C3N4 Hybrids with Improved Photostability and Visible Light Photocatalytic Activity [J].
Xu, Yao ;
Zhang, Wei-De .
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2015, (10) :1744-1751
[47]   Facile ion-exchange synthesis of urchin-shaped CdS/Bi2S3 heterostructures with enhanced photostability and visible light photocatalytic activity [J].
Yan, Yunhui ;
Zhou, Zhaoxian ;
Li, Wuqi ;
Zhu, Yanjie ;
Cheng, Yun ;
Zhao, Fengying ;
Zhou, Jianguo .
RSC ADVANCES, 2014, 4 (73) :38558-38567
[48]   Synthesis of Fullerene- and Nanotube-Like SnS2 Nanoparticles and Sn/S/Carbon Nanocomposites [J].
Yella, Aswani ;
Mugnaioli, Enrico ;
Therese, Helen Annal ;
Panthoefer, Martin ;
Kolb, Ute ;
Tremel, Wolfgang .
CHEMISTRY OF MATERIALS, 2009, 21 (12) :2474-2481
[49]   Monodisperse SnS2 Nanosheets for High-Performance Photocatalytic Hydrogen Generation [J].
Yu, Jing ;
Xu, Cheng-Yan ;
Ma, Fei-Xiang ;
Hu, Sheng-Peng ;
Zhang, Yu-Wei ;
Zhen, Liang .
ACS APPLIED MATERIALS & INTERFACES, 2014, 6 (24) :22370-22377
[50]   One-step in situ solvothermal synthesis of SnS2/TiO2 nanocomposites with high performance in visible light-driven photocatalytic reduction of aqueous Cr(VI) [J].
Zhang, Yong Cai ;
Li, Jing ;
Xu, Hai Yan .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2012, 123 :18-26