Structural and dielectric properties of Sr substituted BaTi0.8Zr0.2O3 perovskite synthesized via solid state reaction route

被引:1
作者
Ullah, Zaka [1 ]
Rehman, Javed [2 ]
Rehman, Faheem Ur [3 ]
Gulbadan, Shagufta [4 ]
Mahmood, Muhammad Adil [4 ]
Khan, Muhammad Azhar [4 ]
机构
[1] Quaid i Azam Univ, Dept Phys, Islamabad, Pakistan
[2] Balochistan Univ Informat Technol Engn & Manageme, Dept Phys, Quetta 87300, Pakistan
[3] Ural Fed Univ, Grad Sch Econ & Management, Lab Reg & Int Econ, Ekaterinburg, Russia
[4] Islamia Univ Bahawalpur, Inst Phys, Bahawalpur 63100, Pakistan
来源
APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING | 2022年 / 128卷 / 06期
关键词
Perovskite; Ferroelectrics; X-ray diffraction; Dielectric properties; Scanning electron microscope; PHASE-TRANSITION; OPTICAL-PROPERTIES; CERAMICS; BEHAVIOR; MICROSTRUCTURE; POLARIZATION; MECHANISMS; MGO;
D O I
10.1007/s00339-022-05619-5
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Perovskite type Ba1-xSrxZr0.2Ti0.8O3 (with x = 0.0, 0.1, 0.2 and 0.3) ceramics have been synthesized through conventional two-step solid-state reaction method. The structural characterization was done using an X-ray diffraction study. All the compositions reveal a single-phase cubic structure. The dielectric measurements were taken at various temperatures (100 to 300 K) and various frequencies (1 to 500 kHz) for all the prepared compositions. This study reveals that the Ba1-xSrxTi0.8Zr0.2O3 (with x = 0.0, 0.1, 0.2 and 0.3) composition does not transform from normal ferroelectric to relaxor ferroelectric. The diffusivity enhances with increment in Sr concentration in the present composition range. It is observed that with enhancement in Sr content, the transition temperature decreases for all the studied compositions. The decrease in transition temperature may occur due to introducing a smaller ionic radius of Sr2+ at the site of a larger ionic radius of Ba2+. The morphological properties of all the samples are analyzed using scanning electron microscopy images.
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页数:13
相关论文
共 57 条
[31]  
NACEUR H., 2013, ORIENT J CHEM, V29, P937, DOI 10.13005/ojc/290311
[32]  
Nettleton R. E., 1970, Ferroelectrics, V1, P93, DOI 10.1080/00150197008237676
[33]   Structural, morphological and dielectric features of neodymium doped BiFeO3-PbTiO3 electronic system [J].
Pradhan, S. K. ;
Das, S. N. ;
Bhuyan, S. .
MATERIALS TODAY-PROCEEDINGS, 2021, 35 :73-75
[34]   Structural, optical and electrical properties of barium titanate [J].
Rached, A. ;
Wederni, M. A. ;
Khirouni, K. ;
Alaya, S. ;
Martin-Palma, R. J. ;
Dhahri, J. .
MATERIALS CHEMISTRY AND PHYSICS, 2021, 267
[35]   Grain boundary-dominated electrical conduction and anomalous optical-phonon behaviour near the Neel temperature in YFeO3 ceramics [J].
Raut, Subhajit ;
Babu, P. D. ;
Sharma, R. K. ;
Pattanayak, Ranjit ;
Panigrahi, Simanchalo .
JOURNAL OF APPLIED PHYSICS, 2018, 123 (17)
[36]   Structural and dielectric characterization of Sr substituted Ba(Zr,Ti)O3 based functional materials [J].
Reddy, S. Bhaskar ;
Rao, K. Prasad ;
Rao, M. S. Ramachandra .
APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 2007, 89 (04) :1011-1015
[37]  
Safari A., 1996, FERROELECTRICITY MAT
[38]   Effect of the amorphous-to-crystalline transition in Ba0.5Sr0.5TiO3 thin films on optical and microwave dielectric properties [J].
Saravanan, K. Venkata ;
Sudheendran, K. ;
Krishna, M. Ghanashyam ;
Raju, K. C. James .
JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2009, 42 (04)
[39]   Applications of modern ferroelectrics [J].
Scott, J. F. .
SCIENCE, 2007, 315 (5814) :954-959
[40]   Structural, electrical, dielectric properties and conduction mechanism of sol-gel prepared Pr0.75Bi0.05Sr0.1Ba0.1Mn0.98Ti0.02O3 compound [J].
Sekrafi, H. E. ;
Kharrat, A. Ben Jazia ;
Wederni, M. A. ;
Khirouni, K. ;
Chniba-Boudjada, N. ;
Boujelben, W. .
MATERIALS RESEARCH BULLETIN, 2019, 111 :329-337