Optical limiting response of multi-walled carbon nanotube-phthalocyanine nanocomposite in solution and when in poly (acrylic acid)

被引:13
作者
Sekhosana, Kutloano Edward [1 ]
Nyokong, Tebello [1 ]
机构
[1] Rhodes Univ, Dept Chem, POB 94, ZA-6140 Grahamstown, South Africa
基金
新加坡国家研究基金会;
关键词
Nonlinear optical limiting; Clam-shell phthalocyanine; Multiwalled carbon nanotubes; PHOTOPHYSICOCHEMICAL BEHAVIOR; SATURABLE ABSORPTION; PMMA COMPOSITE; DERIVATIVES; NONLINEARITIES; PERFORMANCE; MECHANISM; HYBRID;
D O I
10.1016/j.molstruc.2016.03.067
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Bis{23-(3,4-di-yloxybenzoic acid)-(2(3), 9(10), 16(17), 23(24)-(hexakis-pyridin-3-yloxy phthalocyaninato)) dineodymium (III) acetate (3) is linked to amino-functionalized multi-walled carbon nanotubes (MWCNT) to form 3-MWCNT. Z-scan technique was employed to experimentally determine the nonlinear absorption coefficient from the open-aperture data. The limiting threshold values as low as 0.045 J cm-2 were found in solution. The conjugate (3-MWCNT) gave better optical limiting behavior than complex 3 alone. (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码:140 / 146
页数:7
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