Polystyrene-Bound Hydrazone Schiff Base Molybdenum Complex: Synthesis, Characterization, and Application as a Reusable Heterogeneous Catalyst in the Oxidation of Sulfides

被引：0
作者：
Kargar, H. [1 ]
Ghorbani, M. [2 ]
Fallah-Mehrjardi, M. [2 ]
机构：
[1] Ardakan Univ, Fac Engn, Dept Chem Engn, Ardakan, Iran
[2] Payame Noor Univ, Dept Chem, Tehran 193954697, Iran
来源：
RUSSIAN JOURNAL OF ORGANIC CHEMISTRY | 2022年 / 58卷 / 06期
关键词：
dioxomolybdenum(VI); hydrazone Schiff base; heterogeneous catalyst; reusability; oxidation of sulfide; CRYSTAL-STRUCTURE; EFFICIENT; SITE;
D O I：
10.1134/S1070428022060148
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A dioxomolybdenum hydrazone Schiff base complex immobilized on chloromethylated polystyrene [MoO2L@CMP] was synthesized and characterized by various spectroscopic techniques like FT-IR, UV-Vis, DRS, SEM and EDAX. Its catalytic activity was investigated in the oxidation of various aliphatic and aromatic sulfides using H2O2 as an oxidant in ethanol as a green solvent under reflux conditions. The catalyst could readily be separated from the reaction mixture and reused in subsequent reactions with no significant loss of activity.
引用
收藏
页码：850 / 857
页数：8
相关论文
共 37 条
  • [1] Highly Efficient and Selective Oxidation of Sulfides to Sulfones with Hydrogen Peroxide Under Ultrasonic Irradiation Catalyzed by Copper(II) Schiff Base Complex Supported on Mesoporous MCM-41
    Ardakani, Mehdi Hatefi
    Saeednia, Samira
    Sabet, Mohammad
    [J]. SILICON, 2019, 11 (04) : 1775 - 1781
  • [2] Mixed ligand complex via zinc(II)-mediated in situ oxidative heterocyclization of hydrochloride salt of 2-chlorobenzaldehyde hydralazine hydrazone as potential of antihypertensive agent
    Bakale, Raghavendra P.
    Naik, Ganesh N.
    Mangannavar, Chandrashekhar V.
    Muchchandi, Iranna S.
    Shcherbakov, I. N.
    Frampton, Chris
    Gudasi, Kalagouda B.
    [J]. EUROPEAN JOURNAL OF MEDICINAL CHEMISTRY, 2014, 73 : 38 - 45
  • [3] Green oxidation of sulfides in solvent-free condition by reusable novel Mo(VI) complex anchored on magnetite as a high-efficiency nanocatalyst with eco-friendly aqueous H2O2
    Bezaatpour, Abolfazl
    Askarizadeh, Elham
    Akbarpour, Shadab
    Amiria, Mandana
    Babaei, Behnam
    [J]. MOLECULAR CATALYSIS, 2017, 436 : 199 - 209
  • [4] Merrifield resin supported peroxomolybdenum(VI) compounds: recoverable heterogeneous catalysts for the efficient, selective and mild oxidation of organic sulfides with H2O2
    Boruah, Jeena Jyoti
    Das, Siva Prasad
    Ankireddy, Seshadri Reddy
    Gogoi, Sandhya Rani
    Islam, Nashreen S.
    [J]. GREEN CHEMISTRY, 2013, 15 (10) : 2944 - 2959
  • [5] Dalia S.A., 2018, INT J CHEM STUD, V6, P2859
  • [6] cis-Dioxido-molybdenum(VI) complexes of tridentate ONO hydrazone Schiff base: Synthesis, characterization, X-ray crystal structure, DFT calculation and catalytic activity
    Ebrahimipour, S. Yousef
    Khabazadeh, Hojatollah
    Castro, Jesus
    Sheikhshoaie, Iran
    Crochet, Aurelien
    Fromm, Katharina M.
    [J]. INORGANICA CHIMICA ACTA, 2015, 427 : 52 - 61
  • [7] Fabrication of molybdenum-substituted tungstophosphoric acid immobilized onto functionalized graphene oxide: Visible light-induced photocatalyst for selective oxidation of sulfides to sulfoxides
    Fakhri, Hanieh
    Mahjoub, Alireza
    Nejat, Razieh
    Maridiroosi, Anasheh
    [J]. INORGANIC CHEMISTRY COMMUNICATIONS, 2021, 123
  • [8] A new chloromethylation method based on polystyrene-divinylbenzene
    Fu, Yuli
    Huang, Xiaobei
    Zhong, Shihua
    Yi, Wen-Jun
    Li, Li-Jun
    [J]. CHEMICAL PAPERS, 2019, 73 (09): : 2183 - 2188
  • [9] Synthesis, characterization and oxygen atom transfer reactivity of a pair of Mo(IV)O- and Mo(VI)O2-enedithiolate complexes - a look at both ends of the catalytic transformation
    Ghosh, Ashta C.
    Samuel, Prinson P.
    Schulzke, Carola
    [J]. DALTON TRANSACTIONS, 2017, 46 (23) : 7523 - 7533
  • [10] Synthesis of Sulfones via Ru(II)-Catalyzed Sulfination of Boronic Acids
    Gulbe, Krista
    Turks, Maris
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 2020, 85 (08) : 5660 - 5669
1234