Solvothermal Synthesis and Characterization of a New 3D Zn (II) Coordination Polymer With (3,4)-Connected Topology

被引：2

作者：

Wei, Zongwu ^{[1
]}

Mu, Xiao ^{[1
]}

Chen, Ye ^{[1
]}

机构：

[1] Guangxi Univ, Coll Resources & Met, Nanning 530004, Peoples R China

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2016年 / 46卷 / 01期

关键词：

Zn(II) compound; 1; 2; 4; 5-benzenetetracarboxylic acid; fsh topology; luminescence; METAL-ORGANIC FRAMEWORKS;

D O I：

10.1080/15533174.2014.900797

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new Zn(II) compound, namely [Zn(btec)(0.5)(bpe)(0.5)(DMF)](n) (1 H(4)btec = 1,2,4,5-benzenetetracarboxylic acid, bpe = 1,2-di(4-pyridyl)ethylene, DMF = N,N'-dimethylformamide), has been solvothermally synthesized and characterized by elemental analysis and single-crystal X-ray diffraction. Compound 1 features a complicated three-dimensional (3D) framework with (3,4)-connected fsh topology. Moreover, this compound emits strong luminescence at room temperature.

引用

页码：147 / 150

页数：4

共 17 条

[1]

[Anonymous], 1996, SADABS

[2] Eight Two-Dimensional and Three-Dimensional Metal Organic Frameworks Based on a Flexible Tetrakis(imidazole) Ligand: Synthesis, Topological Structures, and Photo luminescent Properties [J].

Bai, Hong-Ye ;

Ma, Jian-Fang ;

Yang, Jin ;

Zhang, Lai-Ping ;

Ma, Ji-Cheng ;

Liu, Ying-Ying .

CRYSTAL GROWTH & DESIGN, 2010, 10 (04) :1946-1959

[3] Tuning Structural Topologies of Three Photoluminescent Metal-Organic Frameworks via Isomeric Biphenyldicarboxylates [J].

Guo, Feng ;

Wang, Fei ;

Yang, Hui ;

Zhang, Xiuling ;

Zhang, Jian .

INORGANIC CHEMISTRY, 2012, 51 (18) :9677-9682

[4] New approaches to the analysis of high connectivity materials:: Design frameworks based upon 44- and 63-subnet tectons [J].

Hill, RJ ;

Long, DL ;

Champness, NR ;

Hubberstey, P ;

Schröder, M .

ACCOUNTS OF CHEMICAL RESEARCH, 2005, 38 (04) :335-348

[5] Organically templated (3,8)-connected microporous heterometallic Zn(II)-Sr(II) coordination polymer [J].

Kang, Xin-Ping ;

Zhu, Li-Hua ;

Hu, Ying-Shuang ;

An, Zhe .

INORGANIC CHEMISTRY COMMUNICATIONS, 2013, 29 :11-13

[6] Crystal structures and magnetism of infinite alternating chains arranged by paddle-wheel dinuclear copper and mononuclear copper units [J].

Li, Huijun ;

Yao, Hongchang ;

Zhang, Erpeng ;

Jia, Yanyuan ;

Hou, Hongwei ;

Fan, Yaoting .

DALTON TRANSACTIONS, 2011, 40 (37) :9388-9393

[7] Syntheses and characterizations of zinc(II) compounds containing three-dimensional interpenetrating diamondoid networks constructed by mixed ligands [J].

Li, XJ ;

Cao, R ;

Sun, DF ;

Bi, WH ;

Wang, YQ ;

Li, X ;

Hong, MC .

CRYSTAL GROWTH & DESIGN, 2004, 4 (04) :775-780

[8] Metal-directed topological diversity of three fluorescent metal-organic frameworks based on a new tetracarboxylate strut [J].

Lou, Xin-Hua ;

Xu, Chen ;

Li, Hong-Mei ;

Wang, Zhi-Qiang ;

Guo, Hui ;

Xue, Dong-Xu .

CRYSTENGCOMM, 2013, 15 (23) :4606-4610

[9]

Sheldrick G.M., 1993, PROGRAM CRYSTAL STRU

[10] Mid-infrared emissive InAsSb quantum dots grown by metal-organic chemical vapor deposition [J].

Tang Xiaohong ;

Zhang Baolin ;

Yin Zongyou .

CRYSTENGCOMM, 2013, 15 (03) :604-608

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