Electrochemical Deposition of Zinc Sulfide from a Na2SO3-Based Electrolyte

被引：3
作者：
Demidenko, I. V. [1 ]
Ishimov, V. M. [1 ]
机构：
[1] Shevchenko Pridnestrovie State Univ, MD-3300 Tiraspol, Moldova
来源：
SURFACE ENGINEERING AND APPLIED ELECTROCHEMISTRY | 2022年 / 58卷 / 02期
关键词：
electrochemical deposition; semiconducting film; zinc sulfide; CHEMICAL BATH DEPOSITION; THIN-FILMS; ZNS; ELECTRODEPOSITION; PRESSURE; GROWTH;
D O I：
10.3103/S1068375522020028
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
Aspects of electrochemical deposition of zinc sulfide from an aqueous electrolyte based on sodium sulfite and zinc sulfate are addressed, and conditions for electrochemical synthesis of ZnS films are identified. The range of potentials for ZnS deposition is demonstrated to be limited by the potential at which the current reaches the critical value associated with diffusion-limited electrochemical reduction of the sulfite ion. The synthesized films are found to contain excess sulfur, which can be removed by thermal treatment to obtain stoichiometrically correct films. A reaction mechanism leading to the formation of zinc sulfide is proposed.
引用
收藏
页码：109 / 115
页数：7
相关论文
共 50 条
  • [21] One-step wet chemical deposition of NiO from the electrochemical reduction of nitrates in ionic liquid based electrolytes
    Azaceta, Eneko
    Ngo Thi Tuyen
    Pickup, David F.
    Rogero, Celia
    Enrique Ortega, J.
    Miguel, Oscar
    Grande, Hans-Jurgen
    Tena-Zaera, Ramon
    ELECTROCHIMICA ACTA, 2013, 96 : 261 - 267
  • [22] The Electrochemical Characterization of Nanostructured Bi2Se3 Thin Films in an Aqueous Na Electrolyte
    Meija, Raimonds
    Lazarenko, Vitalijs
    Skrastina, Anna
    Rublova, Yelyzaveta
    Andzane, Jana
    Voikiva, Vanda
    Viksna, Arturs
    Erts, Donats
    BATTERIES-BASEL, 2022, 8 (03):
  • [23] Electrochemical Deposition of Bi2(Te,Se)3 Nanowire Arrays on Si
    Limmer, Steven J.
    Yelton, W. Graham
    Siegal, Michael P.
    Lensch-Falk, Jessica L.
    Pillars, Jamin
    Medlin, Douglas L.
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2012, 159 (04) : D235 - D239
  • [24] Effect of sulfurization time on the properties of copper zinc tin sulfide thin films grown by electrochemical deposition
    Aldalbahi, Ali
    Mkawi, E. M.
    Ibrahim, K.
    Farrukh, M. A.
    SCIENTIFIC REPORTS, 2016, 6
  • [25] Electrochemical Deposition of Iridium onto Gallium Arsenide from a Sulfamate Electrolyte Based on Hexachloroiridic(IV) Acid
    Bekezina, T. P.
    Vaisbekker, M. S.
    Burmistrova, V. A.
    Bozhkov, V. G.
    RUSSIAN JOURNAL OF APPLIED CHEMISTRY, 2023, 96 (12) : 1063 - 1075
  • [26] Pulsed laser deposition from ZnS and Cu2SnS3 multicomponent targets
    Ettlinger, Rebecca Bolt
    Cazzaniga, Andrea
    Canulescu, Stela
    Pryds, Nini
    Schou, Jorgen
    APPLIED SURFACE SCIENCE, 2015, 336 : 385 - 390
  • [27] Electrochemical Self-Assembly of Oriented Zinc Oxide Film from Polyethylene Oxide Containing Electrolyte
    Ju, Xiaohui
    Feng, Wei
    Fujii, Akihiko
    Ozaki, Masanori
    JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 2009, 9 (03) : 1766 - 1771
  • [28] THE PECULIARITIES OF ELECTROCHEMICAL DEPOSITION AND MORPHOLOGY OF Zn-Mn ALLOY COATINGS OBTAINED FROM PYROPHOSPHATE ELECTROLYTE
    Bucko, Mihael M.
    Stevanovic, Sanja I.
    Tomic, Milorad V.
    Pavlovic, Miomir G.
    Bajat, Jelena B.
    HEMIJSKA INDUSTRIJA, 2011, 65 (03) : 295 - 303
  • [29] Zinc oxide films grown by galvanic deposition from 99% metals basis zinc nitrate electrolyte
    Calnan, S.
    Riedel, W.
    Gledhill, S.
    Stannowski, B.
    Schlatmann, R.
    Lux-Steiner, M. Ch.
    JOURNAL OF MATERIALS CHEMISTRY A, 2014, 2 (25) : 9626 - 9635
  • [30] Ultrasensitive electrochemical biosensors based on zinc sulfide/graphene hybrid for rapid detection of SARS-CoV-2
    Sarwar, Shatila
    Lin, Mao-Chia
    Amezaga, Carolina
    Wei, Zhen
    Iyayi, Etinosa
    Polk, Haseena
    Wang, Ruigang
    Wang, Honghe
    Zhang, Xinyu
    ADVANCED COMPOSITES AND HYBRID MATERIALS, 2023, 6 (01)
12345