Electrochemical Deposition of Zinc Sulfide from a Na2SO3-Based Electrolyte

被引：3
作者：
Demidenko, I. V. [1 ]
Ishimov, V. M. [1 ]
机构：
[1] Shevchenko Pridnestrovie State Univ, MD-3300 Tiraspol, Moldova
来源：
SURFACE ENGINEERING AND APPLIED ELECTROCHEMISTRY | 2022年 / 58卷 / 02期
关键词：
electrochemical deposition; semiconducting film; zinc sulfide; CHEMICAL BATH DEPOSITION; THIN-FILMS; ZNS; ELECTRODEPOSITION; PRESSURE; GROWTH;
D O I：
10.3103/S1068375522020028
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
Aspects of electrochemical deposition of zinc sulfide from an aqueous electrolyte based on sodium sulfite and zinc sulfate are addressed, and conditions for electrochemical synthesis of ZnS films are identified. The range of potentials for ZnS deposition is demonstrated to be limited by the potential at which the current reaches the critical value associated with diffusion-limited electrochemical reduction of the sulfite ion. The synthesized films are found to contain excess sulfur, which can be removed by thermal treatment to obtain stoichiometrically correct films. A reaction mechanism leading to the formation of zinc sulfide is proposed.
引用
收藏
页码：109 / 115
页数：7
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