X-ray crystal structure of (tetraphenylimidodiphosphinato)silver(I) an unexpected tetranuclear complex with two modes of coordination of silver

被引：43

作者：

Rudler, H ^{[1
]}

Denise, B ^{[1
]}

Gregorio, JR ^{[1
]}

Vaissermann, J ^{[1
]}

机构：

[1] UNIV PARIS 06,CHIM MET TRANSIT LAB,URA 419,F-75252 PARIS 5,FRANCE

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 23期

关键词：

D O I：

10.1039/a706430f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Potassium tetraphenylimidodiphosphinate reacts with silver nitrate to give, upon recrystallization from ethanol, an unexpected tetranuclear complex [Ag{N(OPPh2)(2)}](4) . 2EtOH, the structure of which is established by X-ray crystallography; preliminary results concerning its use as a catalyst for the aerobic co-oxidation of alkenes and aldehydes are described.

引用

页码：2299 / 2300

页数：2

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