Investigation of hydrogenation of Dibenzyltoluene as liquid organic hydrogen carrier

被引:25
作者
Ali, Ahsan [1 ]
Kumar, G. Udaya [1 ]
Lee, Hee Joon [1 ]
机构
[1] Kookmin Univ, Dept Mech Engn, Seoul 02707, South Korea
基金
新加坡国家研究基金会;
关键词
Hydrogenation; Liquid organic hydrogen storage; Raney-Ni; Dibenzyltoluene; Catalytic activity; PERHYDRO-N-ETHYLCARBAZOLE; CATALYTIC-HYDROGENATION; DEHYDROGENATION; STORAGE; KINETICS;
D O I
10.1016/j.matpr.2020.03.232
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
In recent years, Dibenzyltoluene (H0-DBT) is becoming a promising liquid organic hydrogen carrier for hydrogen storage purpose. In this study, the hydrogenation characteristics of H0-DBT were investigated under a pressure of 0.8 MPa. Initially, the catalytic activity of three different catalysts: Raney-Ni, 5% Pd/ Al2O3 and 5% Ru/Al2O3 was examined at 150 and 200 degrees C. Raney-Ni was found to be the best catalyst as compared to others. Moreover, the hydrogenation experiment was conducted over Raney-Ni catalyst to indicate the optimal temperature of the reaction. The results elucidated that 170 degrees C was the optimal reaction temperature which yielded the hydrogen capacity of 1.33 wt%. (c) 2021 Elsevier Ltd. All rights reserved. Selection and peer-review under responsibility of the scientific committee of the International Conference on Advances in Materials Research - 2019.
引用
收藏
页码:1123 / 1127
页数:5
相关论文
共 50 条
  • [21] Hydrogenation of liquid organic hydrogen carrier systems using multicomponent gas mixtures
    Jorschick, H.
    Vogl, M.
    Preuster, P.
    Boesmann, A.
    Wasserscheid, P.
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2019, 44 (59) : 31172 - 31182
  • [22] Hydrogenation of 9-ethylcarbazole as a prototype of a liquid hydrogen carrier
    Eblagon, Katarzyna Morawa
    Rentsch, Daniel
    Friedrichs, Oliver
    Remhof, Arndt
    Zuettel, Andreas
    Ramirez-Cuesta, A. J.
    Tsang, Shik Chi
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2010, 35 (20) : 11609 - 11621
  • [23] A highly adaptable Ni catalyst for Liquid Organic Hydrogen Carriers hydrogenation
    Ding, Yuhang
    Dong, Yuan
    Zhang, Heshun
    Zhao, Yinheng
    Yang, Ming
    Cheng, Hansong
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2021, 46 (53) : 27026 - 27036
  • [24] Novel Catalysts for Dibenzyltoluene as a Potential Liquid Organic Hydrogen Carrier Use-A Mini-review
    Sisakova, Katarina
    Podrojkova, Natalia
    Orinakova, Renata
    Orinak, Andrej
    ENERGY & FUELS, 2021, 35 (09) : 7608 - 7623
  • [25] Stress tolerance assessment of dibenzyltoluene-based liquid organic hydrogen carriers
    Modisha, Phillimon
    Bessarabov, Dmitri
    SUSTAINABLE ENERGY & FUELS, 2020, 4 (09) : 4662 - 4670
  • [26] A novel liquid organic hydrogen carrier system based on catalytic peptide formation and hydrogenation
    Hu, Peng
    Fogler, Eran
    Diskin-Posner, Yael
    Iron, Mark A.
    Milstein, David
    NATURE COMMUNICATIONS, 2015, 6
  • [27] Catalytic hydrogenation and dehydrogenation performance of 9-ethylcarbazole as a liquid organic hydrogen carrier
    Ahsan Ali
    Udaya Kumar G
    Hee Joon Lee
    Journal of Mechanical Science and Technology, 2019, 33 : 5561 - 5569
  • [28] Recent Advances in Homogeneous/Heterogeneous Catalytic Hydrogenation and Dehydrogenation for Potential Liquid Organic Hydrogen Carrier (LOHC) Systems
    Cho, Jun-Young
    Kim, Hahyeon
    Oh, Jeong-Eun
    Park, Boyoung Y.
    CATALYSTS, 2021, 11 (12)
  • [29] Liquid Organic Hydrogen Carrier Concepts and Catalysts for Hydrogenation and Dehydrogenation Reactions
    Cabrera, Gerardo
    Mora, Malka
    Gil-Burgos, Juan P.
    Visbal, Renso
    Machuca-Martinez, Fiderman
    Mosquera-Vargas, Edgar
    MOLECULES, 2024, 29 (20):
  • [30] Dynamic power supply by hydrogen bound to a liquid organic hydrogen carrier
    Fikrt, Andre
    Brehmer, Richard
    Milella, Vito-Oronzo
    Mueller, Karsten
    Boesmann, Andreas
    Preuster, Patrick
    Alt, Nicolas
    Schluecker, Eberhard
    Wasserscheid, Peter
    Arlt, Wolfgang
    APPLIED ENERGY, 2017, 194 : 1 - 8