Investigation of hydrogenation of Dibenzyltoluene as liquid organic hydrogen carrier

被引:25
|
作者
Ali, Ahsan [1 ]
Kumar, G. Udaya [1 ]
Lee, Hee Joon [1 ]
机构
[1] Kookmin Univ, Dept Mech Engn, Seoul 02707, South Korea
基金
新加坡国家研究基金会;
关键词
Hydrogenation; Liquid organic hydrogen storage; Raney-Ni; Dibenzyltoluene; Catalytic activity; PERHYDRO-N-ETHYLCARBAZOLE; CATALYTIC-HYDROGENATION; DEHYDROGENATION; STORAGE; KINETICS;
D O I
10.1016/j.matpr.2020.03.232
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
In recent years, Dibenzyltoluene (H0-DBT) is becoming a promising liquid organic hydrogen carrier for hydrogen storage purpose. In this study, the hydrogenation characteristics of H0-DBT were investigated under a pressure of 0.8 MPa. Initially, the catalytic activity of three different catalysts: Raney-Ni, 5% Pd/ Al2O3 and 5% Ru/Al2O3 was examined at 150 and 200 degrees C. Raney-Ni was found to be the best catalyst as compared to others. Moreover, the hydrogenation experiment was conducted over Raney-Ni catalyst to indicate the optimal temperature of the reaction. The results elucidated that 170 degrees C was the optimal reaction temperature which yielded the hydrogen capacity of 1.33 wt%. (c) 2021 Elsevier Ltd. All rights reserved. Selection and peer-review under responsibility of the scientific committee of the International Conference on Advances in Materials Research - 2019.
引用
收藏
页码:1123 / 1127
页数:5
相关论文
共 50 条
  • [1] Integration of hydrogenation and dehydrogenation based on dibenzyltoluene as liquid organic hydrogen energy carrier
    Shi, Libin
    Qi, Suitao
    Qu, Jifeng
    Che, Tinghua
    Yi, Chunhai
    Yang, Bolun
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2019, 44 (11) : 5345 - 5354
  • [2] Parametric study of the hydrogenation of dibenzyltoluene and its dehydrogenation performance as a liquid organic hydrogen carrier
    Ahsan Ali
    Udaya Kumar G
    Hee Joon Lee
    Journal of Mechanical Science and Technology, 2020, 34 : 3069 - 3077
  • [3] Parametric study of the hydrogenation of dibenzyltoluene and its dehydrogenation performance as a liquid organic hydrogen carrier
    Ali, Ahsan
    Kumar, Udaya G.
    Lee, Hee Joon
    JOURNAL OF MECHANICAL SCIENCE AND TECHNOLOGY, 2020, 34 (07) : 3069 - 3077
  • [4] Catalytic hydrogenation reaction micro-kinetic model for dibenzyltoluene as liquid organic hydrogen carrier
    Tomic, Aleksandra
    Pomeroy, Brett
    Todic, Branislav
    Likozar, Blaz
    Nikacevic, Nikola
    APPLIED ENERGY, 2024, 365
  • [5] The effects of alumina morphology and Pt electron property on reversible hydrogenation and dehydrogenation of dibenzyltoluene as a liquid organic hydrogen carrier
    Shi, Libin
    Zhou, Yiming
    Tan, Xiao
    Qi, Suitao
    Smith, Kevin J.
    Yi, Chunhai
    Yang, Bolun
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2022, 47 (07) : 4704 - 4715
  • [6] Binary Diffusion Coefficients of the Liquid Organic Hydrogen Carrier System Dibenzyltoluene/Perhydrodibenzyltoluene
    Heller, Andreas
    Rausch, Michael H.
    Schulz, Peter S.
    Wasserscheid, Peter
    Froeba, Andreas P.
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2016, 61 (01): : 504 - 511
  • [7] Hydrogenation of the liquid organic hydrogen carrier compound dibenzyltoluene - reaction pathway determination by 1H NMR spectroscopy
    Do, G.
    Preuster, P.
    Aslam, R.
    Boesmann, A.
    Mueller, K.
    Arlt, W.
    Wasserscheid, P.
    REACTION CHEMISTRY & ENGINEERING, 2016, 1 (03): : 313 - 320
  • [8] Compressed liquid density and thermodynamic modeling for the promising liquid organic hydrogen carrier Benzyltoluene/Dibenzyltoluene
    Zhou, Tianyu
    Yang, Jian
    Meng, Xianyang
    Zhang, Zhicheng
    Wu, Jiangtao
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2025, 102 : 673 - 687
  • [9] Kinetic analysis of dibenzyltoluene hydrogenation on commercial Ru/Al2O3 catalyst for liquid organic hydrogen carrier
    Park, Sanghyoun
    Abdullah, Malik Muhamamd
    Seong, Kwanjae
    Lee, Sangyong
    CHEMICAL ENGINEERING JOURNAL, 2023, 474
  • [10] Hydrogen Storage Prediction in Dibenzyltoluene as Liquid Organic Hydrogen Carrier Empowered with Weighted Federated Machine Learning
    Ali, Ahsan
    Khan, Muhammad Adnan
    Choi, Hoimyung
    MATHEMATICS, 2022, 10 (20)