Nitroxide-mediated controlled free-radical emulsion polymerization of styrene and n-butyl acrylate with a water-soluble alkoxyamine as initiator

被引：110
|
作者：
Nicolas, J
Charleux, B
Guerret, O
Magnet, SP
机构：
[1] Univ Paris 06, Assoc CNRS, UMR 7610, Chim Lab Polymeres, F-75252 Paris 05, France
[2] ATOFINA, Groupement Rech Lacq, F-64170 Lacq, France
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 45期
关键词：
alkoxyamines; emulsions; living polymerization; nitroxides; polymerization;
D O I：
10.1002/anie.200460704
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Latex: Nitroxide-mediated emulsion polymerizations of n-butyl acrylate and styrene were successfully carried out in a multistep process, with a novel water-soluble SG1-based alkoxyamine as initiator. Fast reactions lead to stable latex particles containing polymers with controlled molar masses.
引用
收藏
页码：6186 / 6189
页数：4
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