Crystal structure of the new cobalt tellurite chloride Co5Te4O11Cl4

被引：10

作者：

Becker, Richard ^{[1
]}

Johnsson, Mats

Berger, Helmuth

机构：

[1] Stockholm Univ, Dept Inorgan Chem, S-10691 Stockholm, Sweden

[2] Ecole Polytech Fed Lausanne, Inst Phys Mat Complexe, Lausanne, Switzerland

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2007年 / 633卷 / 03期

关键词：

oxohalides; tellurites; lone-pair elements; crystal structure;

D O I：

10.1002/zaac.200600336

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The crystal structure of the new compound Co5Te4O11Cl4 is described. It crystallizes in the triclinic system, space group P-1 with the unit cell parameters a = 822.26(8) pm, b = 1029.7(1) pm, c = 1031.1(1) pm, alpha = 110.80(1)degrees, beta = 97.950(9)degrees, gamma = 98.260(9)degrees and Z = 2. The structure is layered along the bc-plane and built by [CoO5Cl], [CoO4Cl2] and [CoO4Cl] polyhedra sandwiched by [TeO3E] and [TeO4E] polyhedra. The layers can be regarded as infinite molecules without any net charge and only weak van der Waals forces connect them to each other. The halides and the lone-pair, E, of Te-IV protrude from the layers.

引用

页码：422 / 424

页数：3

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