Thermoanalytical investigation of nanocrystalline iron (II) phosphate obtained by spontaneous precipitation from aqueous solutions

被引：27
|
作者：
Scaccia, S [1 ]
Carewska, M [1 ]
Di Bartolomeo, A [1 ]
Prosini, PP [1 ]
机构：
[1] ENEA, CR Casaccia, IDROCOMB, Hydrogen Project & Fuel Cells, I-00060 Rome, Italy
来源：
THERMOCHIMICA ACTA | 2003年 / 397卷 / 1-2期
关键词：
Fe-3(PO4)(2)center dot 8H(2)O; thermal analysis; nano-sized particles; X-ray powder diffraction;
D O I：
10.1016/S0040-6031(02)00292-7
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
Fe-3(PO4)(2)(.)8H(2)O has been precipitated under supersaturation conditions from deaerated Fe(NH4)(2)(SO4)(2)(.)6H(2)O and K-2-HPO4 aqueous, ethanol-water and iso-propanol-water solutions at pH = 6.5 and ambient temperature. The precipitates have been characterised by TG/DTG/DTA and DSC techniques, chemical analysis, BET, and X-ray powder diffraction. The presence of ethanol and iso-propanol in the spontaneous precipitation process of ferrous phosphate leads to highly crystalline powder. Thermal treatment at 500degreesC yields a poorly crystalline dehydrated iron phosphate. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：135 / 141
页数：7
相关论文
共 50 条
  • [31] The formation of iron(II) sulfides in aqueous solutions
    Harmandas, NG
    Koutsoukos, PG
    JOURNAL OF CRYSTAL GROWTH, 1996, 167 (3-4) : 719 - 724
  • [32] Thermoanalytical study of nimesulide and their recrystallization products obtained from solutions of several alcohols
    D. A. Gálico
    G. L. Perpétuo
    R. A. E. Castro
    O. Treu-Filho
    A. O. Legendre
    M. S. Galhiane
    G. Bannach
    Journal of Thermal Analysis and Calorimetry, 2014, 115 : 2385 - 2390
  • [33] Thermoanalytical study of nimesulide and their recrystallization products obtained from solutions of several alcohols
    Galico, D. A.
    Perpetuo, G. L.
    Castro, R. A. E.
    Treu-Filho, O.
    Legendre, A. O.
    Galhiane, M. S.
    Bannach, G.
    JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2014, 115 (03) : 2385 - 2390
  • [34] X-RAY STUDIES ON SULPHIDES OF NICKEL AND IRON OBTAINED BY PRECIPITATION FROM WATER SOLUTIONS
    LUNDQVIST, D
    ARKIV FOR KEMI MINERALOGI OCH GEOLOGI, 1947, 24 (04): : 1 - 7
  • [35] Solvent extraction of nickel(II) from aqueous thiocyanate solutions by tributyl phosphate
    Sato, T
    SOLVENT EXTRACTION RESEARCH AND DEVELOPMENT-JAPAN, 2000, 7 : 44 - 54
  • [36] Foam separation of tributyl phosphate from aqueous solutions - Part II: simulation
    Chang, ZD
    Liu, HZ
    Chen, JY
    SEPARATION AND PURIFICATION TECHNOLOGY, 2000, 19 (1-2) : 137 - 143
  • [37] Adsorption of phosphate ions from aqueous solutions by amorphous silica obtained by acid decomposition of nepheline
    V. Mayorov, Dmitriy
    Gorbacheva, Tamara T.
    COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2021, 627
  • [38] Synthesis of iron-loaded zeolites for removal of ammonium and phosphate from aqueous solutions
    Kim, Kwang Soo
    Park, Jung O.
    Nam, Sang Chul
    Environmental Engineering Research, 2013, 18 (04) : 267 - 276
  • [39] Phosphate adsorption performance and mechanisms by nanoporous biochar–iron oxides from aqueous solutions
    Zhaoran Zhang
    Haiqin Yu
    Rixin Zhu
    Xue Zhang
    Liangguo Yan
    Environmental Science and Pollution Research, 2020, 27 : 28132 - 28145
  • [40] SOLVENT EXTRACTION OF IRON(III) FROM AQUEOUS PERCHLORIC ACID SOLUTIONS BY TRIBUTYL PHOSPHATE
    AGGETT, J
    CLARK, TE
    JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1970, 32 (06): : 2037 - &
12345