The synthesis and molecular structure of [TmPh]2Pb:: a complex with an 'inverted' η4-coordination mode for the tris(2-mercapto-1-phenylimidazolyl)hydroborato ligand

被引：50

作者：

Bridgewater, BM ^{[1
]}

Parkin, G ^{[1
]}

机构：

[1] Columbia Univ, Dept Chem, New York, NY 10027 USA

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2000年 / 3卷 / 10期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/S1387-7003(00)00136-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The tris(2-mercaptoimidazolyl)borate lead complex, [Tm-Ph](2)Pb, may be synthesized by reaction of Pb(ClO4)(2) with 2 equivalents of [Tm-Ph]Li. The molecular structure of [Tm-Ph](2)Pb has been determined by X-ray diffraction, revealing that it possesses an unusual structure with an inverted eta(4)-coordination mode for the [Tm-Ph] ligand which includes a Ph ... H-B interaction, (C) 2000 Elsevier Science S.A. All rights reserved.

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页码：534 / 536

页数：3

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