Spectrophotometric study of dehalogenation of benzyl halides with nickel in aprotic dipolar solvents in the presence of oxygen

被引：0

作者：

Egorov, A. M. ^{[1
]}

Novikova, A. N. ^{[2
]}

Stepanova, E. V. ^{[1
]}

机构：

[1] Tula State Univ, Pr Lenina 92, Tula 300600, Russia

[2] FSBI Tula Interreg Vet Lab, Tula, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2016年 / 86卷 / 02期

关键词：

nickel; benzyl halide; oxygen; dipolar aprotic solvent; spectrophotometry; CHARGE-TRANSFER ABSORPTION; MECHANISM; KINETICS; BROMIDE; NI(100); SIMS; XPS;

D O I：

10.1134/S1070363216020079

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Oxidative dissolution of nickel in the benzyl halogenide - dipolar aprotic solvent system in the presence of air oxygen proceeds with the formation of benzaldehyde, benzyl alcohol, 1,2-diphenylethane, and trace amounts of 4,4'-ditolyl. Spectrophotometry studies have revealed that the oxidation products are formed in the solution rather than at the nickel surface. It has been shown that the oxygen adsorbed at the nickel surface practically does not pass into the solution.

引用

页码：251 / 255

页数：5

共 3 条

[1] Spectrophotometric study of dehalogenation of benzyl halides with nickel in aprotic dipolar solvents in the presence of oxygen
А. М. Egorov
А. N. Novikova
Е. V. Stepanova
Russian Journal of General Chemistry, 2016, 86 : 251 - 255
[2] Effects arising from the replacement of aprotic dipolar solvents with ionic liquids in the nickel-catalyzed reduction of aryl chlorides
Prikhod'ko, S. A.
Popov, A. G.
Adonin, N. Yu
MOLECULAR CATALYSIS, 2018, 461 : 19 - 25
[3] Study on Electrolyte Stability and Oxygen Reduction Reaction Mechanisms in the Presence of Manganese Oxide Catalysts for Aprotic Lithium-Oxygen Batteries
Augustin, Matthias
Fenske, Daniela
Parisi, Juergen
ENERGY TECHNOLOGY, 2016, 4 (12) : 1531 - 1542

← 1 →