Transformation of a 1D to 3D coordination polymer mediated by low temperature lattice solvent loss

被引：29

作者：

Chesman, Anthony S. R. ^{[1
]}

Turner, David R. ^{[1
]}

Deacon, Glen B. ^{[1
]}

Batten, Stuart R. ^{[1
]}

机构：

[1] Monash Univ, Sch Chem, Clayton, Vic 3800, Australia

来源：

CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 27期

基金：

澳大利亚研究理事会;

关键词：

MECHANOCHEMICAL PREPARATION; STRUCTURAL TRANSFORMATIONS; METAL-COMPLEXES; NETWORKS; TRINUCLEAR; FRAMEWORK; CRYSTAL; NETS;

D O I：

10.1039/c0cc00711k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The desolvation of lattice methanol from between the 1D chains in {[Cu(4,4'-bipyridine)(ccnm)(2)]center dot 4MeOH} (ccnm = carbamoylcyanonitrosomethanide) under ambient conditions, a weight loss of 22.4%, results in a solid state conversion to the 3D network [Cu(4,4'-bipyridine)(ccnm)(2)].

引用

页码：4899 / 4901

页数：3

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