Lithium tetrakis(tri-tert-butoxysilane-thiolato)gallate(III)

被引：3

作者：

Baranowska, K

Chojnacki, J

Wojnowski, W

Wurster, E

机构：

[1] Gdansk Tech Univ, Dept Chem, PL-80952 Gdansk, Poland

[2] Univ Karlsruhe TH, Inst Anorgan Chem, D-76128 Karlsruhe, Germany

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2002年 / 58卷

关键词：

D O I：

10.1107/S160053680202055X

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, Li[Ga(C12H27O3SSi)(4)], has been obtained as a by-product of the reaction of a metastable GaBr solution with ((BuO)-Bu-t)(3)SiSLi. The asymmetric unit is composed of two separate molecules. Each lithium cation is coordinated by two O atoms from butoxy groups of the ligand.

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页码：M728 / M729

页数：2

相关论文

共 15 条

[1] Cobalt(II) tri-tert-butoxysilanethiolates:: in search of models for catalytic metal site of liver alcohol dehydrogenase [J].

Becker, B ;

Pladzyk, A ;

Konitz, A ;

Wojnowski, W .

APPLIED ORGANOMETALLIC CHEMISTRY, 2002, 16 (09) :517-524

[2]

Becker B, 2001, Z ANORG ALLG CHEM, V627, P280, DOI 10.1002/1521-3749(200102)627:2<280::AID-ZAAC280>3.0.CO

[3]

2-G

[4]

Becker B, 2001, Z ANORG ALLG CHEM, V627, P271, DOI 10.1002/1521-3749(200102)627:2<271::AID-ZAAC271>3.0.CO

[5]

2-G

[6]

Chojnacki J, 2001, Z KRIST-NEW CRYST ST, V216, P198

[7] Aluminum(I) and gallium(I) compounds: Syntheses, structures, and reactions [J].

Dohmeier, C ;

Loos, D ;

Schnockel, H .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1996, 35 (02) :129-149

[8] Synthesis and reactions of triphenylsilanethiolato complexes of manganese(II), iron(II), cobalt(II), and nickel(II) [J].

Komuro, T ;

Kawaguchi, H ;

Tatsumi, K .

INORGANIC CHEMISTRY, 2002, 41 (20) :5083-5090

[9] Preparation of ruthenium silanethiolato complexes and their reactions with sulfur dioxide;: possible models for the activation of SO2 in the homogeneously catalyzed Claus reactions [J].

Kovacs, I ;

Pearson, C ;

Shaver, A .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2000, 596 (1-2) :193-203

[10]

PIEKOS E, 1962, Z ANORG ALLG CHEM, V318, P212