Carborane radical anions:: spectroscopic and electronic properties of a carborane radical anion with a 2n+3 skeletal electron count

被引：57
作者：
Fox, Mark A.
Nervi, Carlo
Crivello, Antonella
Low, Paul J.
机构：
[1] Univ Durham, Dept Chem, Durham DH1 3LE, England
[2] Univ Turin, Dept Chem IFM, I-10125 Turin, Italy
来源：
CHEMICAL COMMUNICATIONS | 2007年 / 23期
基金：
英国工程与自然科学研究理事会;
关键词：
D O I：
10.1039/b700110j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
One-electron reduction of the well-known carborane 1,2-Ph(2)-1,2- C(2)B(10)H(10) (1) gives rise to a stable carborane radical anion ([1](-)) with a true 2n + 3 cluster electron count; the geometry of ([1](-)) features an elongated C...C cage distance but no significant pi-bonding interactions between the cage and the phenyl substituents.
引用
收藏
页码：2372 / 2374
页数：3
相关论文
共 33 条
  • [1] BILEVICH KA, 1965, B ACAD SCI USSR CH, P1887
  • [2] Binder H, 1999, Z ANORG ALLG CHEM, V625, P1059, DOI 10.1002/(SICI)1521-3749(199907)625:7<1059::AID-ZAAC1059>3.0.CO
  • [3] 2-#
  • [4] Exo-π-bonding to an ortho-carborane hypercarbon atom:: systematic icosahedral cage distortions reflected in the structures of the fluoro-, hydroxy- and amino-carboranes, 1-X-2-Ph-1,2C2B10H10 (X = F, OH or NH2) and related anions
    Boyd, LA
    Clegg, W
    Copley, RCB
    Davidson, MG
    Fox, MA
    Hibbert, TG
    Howard, JAK
    Mackinnon, A
    Peace, RJ
    Wade, K
    [J]. DALTON TRANSACTIONS, 2004, (17) : 2786 - 2799
  • [5] A PENTUPLY-BRIDGING CARBONYL GROUP - CRYSTAL AND MOLECULAR-STRUCTURE OF A SALT OF THE 1-OXO-2-PHENYL-1,2-DICARBADODECABORATE(12) ANION, 1,8-N,N,N',N'-TETRAMETHYLNAPHTHALENEDIAMINEH]+[O(PH)C2B10H10]-
    BROWN, DA
    CLEGG, W
    COLQUHOUN, HM
    DANIELS, JA
    STEPHENSON, IR
    WADE, K
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (12) : 889 - 891
  • [6] Synthesis and structural characterization of closo-exo, exo-nido, and pseudocloso group 1 carborane compounds of the C2B10 system
    Chui, K
    Li, HW
    Xie, ZW
    [J]. ORGANOMETALLICS, 2000, 19 (25) : 5447 - 5453
  • [7] Einholz W, 2002, Z ANORG ALLG CHEM, V628, P258, DOI 10.1002/1521-3749(200201)628:1<258::AID-ZAAC258>3.0.CO
  • [8] 2-X
  • [9] Synthesis of stable dodecaalkoxy derivatives of hypercloso-B12H12
    Farha, OK
    Julius, RL
    Lee, MW
    Huertas, RE
    Knobler, CB
    Hawthorne, MF
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (51) : 18243 - 18251
  • [10] Fox M. A., 2007, Comprehensive Organometallic Chemistry III, P49
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