Transition metal halide salts of N-methylmorpholine:: Synthesis, crystal structures and magnetic properties of N-methylmorpholinium salts of copper(II), cobalt(II) and manganese(II)

被引：54
作者：
Parent, Alexander R.
Landee, Christopher P.
Turnbull, Mark M.
机构：
[1] Clark Univ, Carlson Sch Chem & Biochem, Worcester, MA 01610 USA
[2] Clark Univ, Dept Phys, Worcester, MA 01610 USA
来源：
INORGANICA CHIMICA ACTA | 2007年 / 360卷 / 06期
基金：
美国国家科学基金会;
关键词：
tetrahalometallate; crystal structure; antiferromagnet; methylmorpholine;
D O I：
10.1016/j.ica.2006.10.006
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A family of complexes of N-methylmorpholinium metal halides has been synthesized and analyzed using X-ray crystallography and temperature dependant magnetic susceptibility. The compounds produced include (nmmH)(2)[CuCl4] (1), (nmmH)(2)[CoCl4] (2), (nmmH)2[MnCl4] (3), (nmmH)(2)[CuBr4] (4), (nmmH)(2)[CoBr4] (5), and (nmmH)(2)[MnBr4] (6) [nmmH = N-methylmorpholinium]. The compounds are all isomorphous and exhibit weak one dimensional antiferromagnetic interactions, with a contribution from single-ion anisotropy in the case of the cobalt complexes. (C) 2006 Elsevier B.V. All rights reserved.
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页码：1943 / 1953
页数：11
相关论文
共 23 条
  • [1] New square S=1/2 Heisenberg antiferromagnetic lattices: Pyridinium tetrahalocuprates and bispyrazinecopper(II) tetrafluoroborate
    Albrecht, AS
    Landee, CP
    Slanic, Z
    Turnbull, MM
    [J]. MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1997, 305 : 333 - 340
  • [2] MIXED-DONOR AND MONOMERIC N-DONOR ADDUCTS OF ALANE
    ATWOOD, JL
    BUTZ, KW
    GARDINER, MG
    JONES, C
    KOUTSANTONIS, GA
    RASTON, CL
    ROBINSON, KD
    [J]. INORGANIC CHEMISTRY, 1993, 32 (16) : 3482 - 3487
  • [3] Carlin R. L, 1986, MAGNETOCHEMISTRY
  • [4] LINEAR-CHAIN ANTIFERROMAGNETISM IN [(CH3)4N][MNCL3]
    DINGLE, R
    LINES, ME
    HOLT, SL
    [J]. PHYSICAL REVIEW, 1969, 187 (02): : 643 - +
  • [5] MAGNETISM IN 1-DIMENSIONAL SYSTEMS - HEISENBERG MODEL FOR INFINITE SPIN
    FISHER, ME
    [J]. AMERICAN JOURNAL OF PHYSICS, 1964, 32 (05) : 343 - +
  • [6] Gordon A. J., 1972, CHEMISTS COMPANION H
  • [7] The role of non-classical supramolecular interactions in the structures of 2-amino-4,6-dimethylpyridinium tetrahalocuprate(II) salts
    Haddad, SF
    AlDamen, MA
    Willett, RD
    [J]. INORGANICA CHIMICA ACTA, 2006, 359 (02) : 424 - 432
  • [8] IBERS JA, 1992, INT TABLES CRYSTALLO, VC
  • [9] Thermodynamics of spin S=1/2 antiferromagnetic uniform and alternating-exchange Heisenberg chains
    Johnston, DC
    Kremer, RK
    Troyer, M
    Wang, X
    Klümper, A
    Bud'ko, SL
    Panchula, AF
    Canfield, PC
    [J]. PHYSICAL REVIEW B, 2000, 61 (14) : 9558 - 9606
  • [10] Synthesis and crystal structures of (C5H7N3Br)3CuBr4 and (C5H8N3)CuBr2:: An isolated tetrahedral CuBr43- anion
    Liu, SH
    Chen, JD
    Liou, LS
    Wang, JC
    [J]. INORGANIC CHEMISTRY, 2001, 40 (25) : 6499 - 6501
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