Metal-mediated polymerization of acrylates: Relevance of radical traps?

被引：36

作者：

Nagel, M

Paxton, WF

Sen, A ^{[1
]}

机构：

[1] Penn State Univ, Dept Chem, University Pk, PA 16802 USA

[2] Univ Delaware, Dept Chem, Newark, DE 19716 USA

来源：

MACROMOLECULES | 2004年 / 37卷 / 25期

关键词：

D O I：

10.1021/ma0485437

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The metal-mediated polymerization of acrylates was studied. The polymerization were performed using oven-dried glassware in a drybox. A synthesis of [1, 2-bis(4, 4-dimethyl-2-oxazoline-2-yl)ethane]copper(II) dichloride was presented. The NMR spectra of polymers were recorded on a Bruker DPX 300 MHz spectrometer to determine the tacticity from triad distributions. The polymer molecular weights were determined against a polystyrene standard by gel permeation chromatography on either a Waters Associates 600 using Millenium 32 software or a Shimadzu chomatograph using EZSTART 7.2 software.

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页码：9305 / 9307

页数：3

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