Effects of high-energy electron irradiation on heavy-metal fluoride glass

被引:11
|
作者
Jiang, N [1 ]
Qiu, J
Silcox, J
机构
[1] Arizona State Univ, Dept Phys & Astron, Tempe, AZ 85287 USA
[2] Chinese Acad Sci, Shanghai Inst Opt & Fine Mech, Photon Craft Project, Shanghai 201800, Peoples R China
[3] Japan Sci & Technol Corp, Shanghai 201800, Peoples R China
[4] Cornell Univ, Sch Appl & Engn Phys, Ithaca, NY 14850 USA
基金
美国国家科学基金会;
关键词
D O I
10.1063/1.1814812
中图分类号
O59 [应用物理学];
学科分类号
摘要
The effects of high-energy (100 keV) electron irradiation have been observed in a heavy-metal fluoride glass using in situ time-resolved electron energy loss spectroscopy in a scanning transmission electron microscope. Formation of F-2 has been observed. The irradiation-induced changes of configuration and composition are discussed based on the evolution of the near-edge fine structures of F K edge. We suggest that the high sensitivity to electron irradiation is due to the existence of nonbridging F in heavy-metal fluoride glasses so that is there is a tendency of the electron irradiation to eliminate nonbridging F in the irradiated region. (C) 2004 American Institute of Physics.
引用
收藏
页码:6230 / 6233
页数:4
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