Alstorisine A, a nor-monoterpenoid indole alkaloid from cecidogenous leaves of Alstonia scholaris

被引：29

作者：

Chen, Ying-Ying ^{[1
,2
,3
]}

Yang, Jing ^{[2
]}

Yang, Xing-Wei ^{[2
]}

Khan, Afsar ^{[2
,4
]}

Liu, Lu ^{[2
,3
]}

Wang, Bei ^{[2
,3
]}

Zhao, Yun-Li ^{[2
]}

Liu, Ya-Ping ^{[2
]}

Ding, Zhong-Tao ^{[1
]}

Luo, Xiao-Dong ^{[1
,2
]}

机构：

[1] Yunnan Univ, Sch Chem Sci & Technol, Minist Educ, Kunming 650091, Peoples R China

[2] Chinese Acad Sci, State Key Lab Phytochem & Plant Resources West Ch, Kunming Inst Bot, Kunming 650201, Peoples R China

[3] Univ Chinese Acad Sci, Beijing 100049, Peoples R China

[4] COMSATS Inst Informat Technol, Dept Chem, Abbottabad 22060, Pakistan

来源：

TETRAHEDRON LETTERS | 2016年 / 57卷 / 16期

关键词：

Alstonia scholaris; Galls; Monoterpenoid indole alkaloid; Absolute configuration; FLIGHT MASS-SPECTROMETRY; RHAZYA-STRICTA; MELODININE E; A-G; LEUCONODINES; LEUCONOXINE; (-)-LEUCONOXINE; IDENTIFICATION; RHAZINILAM; CONTINUUM;

D O I：

10.1016/j.tetlet.2016.03.022

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Alstorisine A (1), a novel nor-monoterpenoid indole alkaloid with 6/5/6/6 fused-ring system, regarded as a key intermediate from melodinine E to mersicarpine, was isolated from the cecidogenous leaves of Alstonia scholaris. Its structure was identified on the basis of extensive spectroscopic analysis and the comparison of experimental and calculated ECDs. A plausible biogenesis was also postulated. (C) 2016 Elsevier Ltd. All rights reserved.

引用

页码：1754 / 1757

页数：4

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