Experimental study of drop size distributions at high phase ratio in liquid-liquid dispersions

An experimental investigation has been carried out in order to analyse the drop size distributions of a liquid-liquid dispersion in a stirred vessel at high phase ratio. Two liquid-liquid systems have been investigated: one at low and one at high coalescence rate. A sampling technique has been developed in order to measure the drop size distributions in the mixer with the help of a laser granulometer. A statistical approach has been attempted to derive the most probable drop size distribution in the mixer and the results have been compared with the experimental primary distributions. The comparison suggests that the energy dissipation cannot be considered as uniformly distributed in the mixer. The mean diameter of the distribution has been correlated to the,global mechanical input power and to the volume phase fraction (phase ratio) for both systems in the frame of the classical Hinze-Kolmogorov theory. The results show that for each volume fraction studied, the mean diameter of the dispersion is a decreasing power law of the Weber number with an exponent equal to -0.6 at low phase ratio. However, it appears that for both systems studied this exponent is a decreasing function of the phase ratio. This result reveals the existence of a more complex breakup mechanism with high phase ratio than that assumed in the theory which has to be discriminated from dampening effect of the dispersed phase upon the turbulent energy of the bulk phase. The study of the secondary distributions mean diameter seems to be in good agreement with the numerical predictions of Stone (Annu. Rev. Fluid Mech. 26 (1994) 65). The ratio between the mean diameter of the primary distribution to the satellite drop mean diameter is a growing function of the viscosity ratio. (C) 2003 Elsevier Science Ltd. All rights reserved.