Modulated self-organization in complex amphiphilic systems

被引:16
|
作者
Fraaije, JGEM [1 ]
Zvelindovsky, AV [1 ]
Sevink, GJA [1 ]
Maurits, NM [1 ]
机构
[1] Univ Groningen, NL-9747 AG Groningen, Netherlands
关键词
block copolymer; morphology; shear; surface; reaction;
D O I
10.1080/08927020008044119
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We discuss novel simulation methods for 3D pattern formation in complex amphiphilic systems. The focus is on the supra-molecular or mesoscopic level. The building blocks consist of sequences of dissimilar monomers. connected in copolymer chain molecules. Internal factors such as composition and architecture of the polymers. but also external factors such as applied shear. embedded reactions and level of confinement control the self-organization phenomena. Specific examples include dynamical pattern formation in polymer surfactant solution, reactive polymer blends and surface directed structure formation in block copolymer liquids. The approach lives in a twilight zone between scientific disciplines. The ambitious goal is the invention of methods For the rational design of truly complex bio-mimicking materials, in which we combine principles from chemical engineering, physics, chemistry and biology. The keyword is self-organization. of course. But do not be mistaken: autonomous self-organization leads to trouble, modulated self-organization leads to beauty.
引用
收藏
页码:131 / 144
页数:14
相关论文
共 50 条
  • [31] Tungsten self-organization nanowires prepared by DC magnetron sputtering
    Verbeno, C. H.
    Krohling, A. C.
    Freitas, T. C.
    Bueno, T. E. P.
    Schettino, M. A., Jr.
    Gonzalez, J. C.
    Larica, C.
    Nascimento, V. P.
    Passamani, E. C.
    APPLIED SURFACE SCIENCE, 2019, 464 : 360 - 366
  • [32] Reticulate reef patterns - antecedent karst versus self-organization
    Schlager, Wolfgang
    Purkis, Sam
    SEDIMENTOLOGY, 2015, 62 (02) : 501 - 515
  • [33] Step arrangement design and nanostructure self-organization on Si surfaces
    Ogino, T
    Hibino, H
    Homma, Y
    APPLIED SURFACE SCIENCE, 1997, 117 : 642 - 651
  • [34] Polymorphic Self-Organization of Lauroyl Peptide in Response to pH and Concentration
    Novelli, Federica
    Strofaldi, Alessandro
    De Santis, Serena
    Del Giudice, Alessandra
    Casciardi, Stefano
    Galantini, Luciano
    Morosetti, Stefano
    Pavel, Nicolae, V
    Masci, Giancarlo
    Scipioni, Anita
    LANGMUIR, 2020, 36 (14) : 3941 - 3951
  • [35] Emergent coral reef patterning via spatial self-organization
    Xi, Haiwei
    Dong, Xiaoli
    Chirayath, Ved
    Gleason, Arthur C. R.
    Purkis, Sam J.
    CORAL REEFS, 2025, 44 (01) : 273 - 289
  • [36] Self-organization processes during deformation of nickel single crystals
    Ekaterina, Alfyorova
    Andrey, Filippov
    MATERIALS CHARACTERIZATION, 2020, 159
  • [37] Self-Organization Initiated by Shear Flow of Mixtures of Polymer Melts
    Gumennyi, I. V.
    Malkin, A. Ya.
    Kulichikhin, V. G.
    POLYMER SCIENCE SERIES A, 2023, 65 (01) : 104 - 110
  • [38] Self-organization of SiGe planar nanowires via anisotropic elastic field
    Liu, Kailang
    Berbezier, Isabelle
    Favre, Luc
    Ronda, Antoine
    David, Thomas
    Abbarchi, Marco
    Gaillard, Philippe
    Frisch, Thomas
    Croset, Bernard
    Aqua, Jeol-Noel
    PHYSICAL REVIEW MATERIALS, 2019, 3 (02):
  • [39] Self-organization of stack-up block copolymers into polymeric supramolecules
    Yuan, Yong J.
    Choi, Ka-Wai
    Wong, Herbert
    NANOSCALE RESEARCH LETTERS, 2007, 2 (02): : 104 - 106
  • [40] Local pH oscillations witness autocatalytic self-organization of biomorphic nanostructures
    Montalti, M.
    Zhang, G.
    Genovese, D.
    Morales, J.
    Kellermeier, M.
    Garcia-Ruiz, J. M.
    NATURE COMMUNICATIONS, 2017, 8