Modulated self-organization in complex amphiphilic systems

被引:16
|
作者
Fraaije, JGEM [1 ]
Zvelindovsky, AV [1 ]
Sevink, GJA [1 ]
Maurits, NM [1 ]
机构
[1] Univ Groningen, NL-9747 AG Groningen, Netherlands
关键词
block copolymer; morphology; shear; surface; reaction;
D O I
10.1080/08927020008044119
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We discuss novel simulation methods for 3D pattern formation in complex amphiphilic systems. The focus is on the supra-molecular or mesoscopic level. The building blocks consist of sequences of dissimilar monomers. connected in copolymer chain molecules. Internal factors such as composition and architecture of the polymers. but also external factors such as applied shear. embedded reactions and level of confinement control the self-organization phenomena. Specific examples include dynamical pattern formation in polymer surfactant solution, reactive polymer blends and surface directed structure formation in block copolymer liquids. The approach lives in a twilight zone between scientific disciplines. The ambitious goal is the invention of methods For the rational design of truly complex bio-mimicking materials, in which we combine principles from chemical engineering, physics, chemistry and biology. The keyword is self-organization. of course. But do not be mistaken: autonomous self-organization leads to trouble, modulated self-organization leads to beauty.
引用
收藏
页码:131 / 144
页数:14
相关论文
共 50 条
  • [21] Modeling self-organization of nano-size vacancy clusters in stochastic systems subjected to irradiation
    Kharchenko, Dmitrii O.
    Kharchenko, Vasyl O.
    Bashtova, Anna I.
    RADIATION EFFECTS AND DEFECTS IN SOLIDS, 2014, 169 (05): : 418 - 436
  • [23] Self-organization of step bunching instability on vicinal substrate
    Pascale, A.
    Berbezier, I.
    Ronda, A.
    Videcoq, A.
    Pimpinelli, A.
    APPLIED PHYSICS LETTERS, 2006, 89 (10)
  • [24] Self-Organization of Graft Copolymers and Retortable iPP-Based Nanoporous Films Thereof
    Defize, Thomas
    Bouyahyi, Miloud
    Rozanski, Artur
    Yang, Lanti
    Patham, Bhaskar
    Sweere, Teun
    Hochstadt, Sebastian
    Hansen, Michael Ryan
    Bernaerts, Katrien, V
    Jasinska-Walc, Lidia
    Duchateau, Rob
    ACS APPLIED POLYMER MATERIALS, 2022, 4 (10) : 6897 - 6907
  • [25] Complex Self-Organization in n-Alkylammonium Sulfobetaine Zwitterions with High Thermal Stabilities and High Expansion Coefficients
    Lange, Alyna
    Holtzheimer, Lea
    Clarke, Coby
    Thuenemann, Andreas F.
    Taubert, Andreas
    LANGMUIR, 2025, 41 (07) : 4422 - 4434
  • [26] Growth of highly oriented crystalline polyaniline films by self-organization
    Sutar, D. S.
    Padma, N.
    Aswal, D. K.
    Deshpande, S. K.
    Gupta, S. K.
    Yakhmi, J. V.
    JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2007, 313 (01) : 353 - 358
  • [27] Synthesis and self-organization of amphiphilic poly(N-vinylpyrrolidone-2,2,3,3-tetrafluoropropyl methacrylate) diblock copolymers in solution and bulk
    O. G. Zamyshlyayeva
    I. V. Deniskina
    A. P. Filippov
    Yu. D. Semchikov
    Polymer Science Series A, 2011, 53 : 691 - 697
  • [28] Self-organization of ripples on Ti irradiated with focused ion beam
    Qian, H. X.
    Zhou, W.
    APPLIED SURFACE SCIENCE, 2012, 258 (06) : 1924 - 1928
  • [29] Self-organization of macromolecules in novel TPU-clay nanocomposites
    Mondal, Manas
    Chattopadhyay, Pijush Kanti
    Setua, D. K.
    Das, N. C.
    Chattopadhyay, S.
    MULTI-FUNCTIONAL MATERIALS AND STRUCTURES III, PTS 1 AND 2, 2010, 123-125 : 435 - +
  • [30] Adsorption and Self-Organization of Dendrimers at Water-Solid Interfaces
    Popa, Ionel
    Longtin, Remi
    Maroni, Plinio
    Papastavrou, Georg
    Borkovec, Michal
    CHIMIA, 2009, 63 (05) : 279 - 282