Inhibition of corrosion of copper by 2,5-dimercapto-1,3,4-thiadiazole in 3.5% NaCl solution

被引:0
作者
Yadav, M. [1 ]
Sharma, Dipti [1 ]
机构
[1] Indian Sch Mines Univ, Dept Appl Chem, Dhanbad 826004, Bihar, India
关键词
Copper; Corrosion inhibition; 2,5-Dimercapto-1,3,4-thiadiazole; TRIAZOLE DERIVATIVES; MEDIA;
D O I
暂无
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
The inhibitor 2,5-dimercapto1,3,4-thiadiazole shows 94.48 percent inhibition efficiency in controlling corrosion of copper in 3.5%NaCl solution at pH 7.0. The mechanistic aspects of corrosion inhibition, based on the results obtained from the weight loss method, potentiostatic polarization study, AC-impedance study, UV-visible absorption study and surface study by FTIR, ESCA and SEM have been discussed. The inhibitor 2,5-dimercapto-1,3,4-thiadiazole appears to inhibit corrosion process through formation of protective film which was found to consist of Cu(I)-inhibitor complex, cuprous chloride, CuCl or CuCl(2)(-) complex ion or both and no oxide of copper on the surface.
引用
收藏
页码:95 / 101
页数:7
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