Ruthenium clay catalyzed chemoselective hydrogenation of unsaturated esters, epoxides, sulfones and phosphonates

被引：10
作者：
Aldea, R [1 ]
Alper, H [1 ]
机构：
[1] Univ Ottawa, Dept Chem, Ottawa, ON K1N 6N5, Canada
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1998年 / 551卷 / 1-2期
基金：
加拿大自然科学与工程研究理事会;
关键词：
hydrogenation; ruthenium; clay;
D O I：
10.1016/S0022-328X(97)00493-2
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Ru-clays were prepared using montmorillonite-PPh2 or montmorillonite-bpy and RuCl3 . H2O. The clays obtained were found to be effective catalysts for the reduction of unsaturated esters, epoxides, sulfones and phosphonates. (C) 1998 Elsevier Science S.A.
引用
收藏
页码：349 / 354
页数：6
相关论文
共 30 条
  • [1] SUPPORTED TRANSITION-METAL COMPLEXES .2. SILICA AS SUPPORT
    ALLUM, KG
    HANCOCK, RD
    HOWELL, IV
    MCKENZIE, S
    PITKETHLY, RC
    ROBINSON, PJ
    [J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1975, 87 (02) : 203 - 216
  • [2] PREPARATION OF LACTONES VIA TRICARBONYLIRON-LACTONE COMPLEXES
    ANNIS, GD
    LEY, SV
    SELF, CR
    SIVARAMAKRISHNAN, R
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1981, (01): : 270 - 277
  • [3] Balogh M, 1993, ORGANIC CHEM USING C, P77
  • [4] BLUMEL J, 1994, INORG CHEM, V33, P5050
  • [5] PALLADIUM-CATALYZED HYDROGENATION OF ALPHA,BETA-UNSATURATED SULFONES AND PHOSPHONATES
    CHO, IS
    ALPER, H
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 1994, 59 (15) : 4027 - 4028
  • [6] CHEMOSELECTIVE HYDROGENATION OF THE DOUBLE-BOND OF VINYL EPOXIDES WITH HOMOGENEOUS PALLADIUM AND IRIDIUM CATALYSTS
    CHO, IS
    LEE, B
    ALPER, H
    [J]. TETRAHEDRON LETTERS, 1995, 36 (34) : 6009 - 6012
  • [7] SYNTHESIS AND CATALYTIC ACTIVITY IN SELECTIVE HYDROGENATION OF PALLADIUM COMPLEXES ANCHORED IN MONTMORILLONITE
    CHOUDARY, BM
    KUMAR, KR
    KANTAM, ML
    [J]. JOURNAL OF CATALYSIS, 1991, 130 (01) : 41 - 51
  • [8] A HIGHLY SELECTIVE MONTMORILLONITE CATALYST FOR HYDROGENATION OF ALKYNES, ALKENYNES, AND ALKADIENES
    CHOUDARY, BM
    VASANTHA, G
    SHARMA, M
    BHARATHI, P
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1989, 28 (04): : 465 - 466
  • [9] FALLING SN, 1990, Patent No. 5077418
  • [10] PRODUCTION OF AN OPTICALLY-ACTIVE SULFOXIDE BY USE OF COLLOIDALLY DISPERSED LAMBDA-TRIS(2,2'-BIPYRIDYL)RUTHENIUM(II) MONTMORILLONITE AS A PHOTOSENSITIZER
    HIKITA, T
    TAMARU, K
    YAMAGISHI, A
    IWAMOTO, T
    [J]. INORGANIC CHEMISTRY, 1989, 28 (11) : 2221 - 2223
123