Yttrium-scandium oxide as high-k gate dielectric for germanium metal-oxide-semiconductor devices

被引:14
作者
Bera, M. K. [1 ]
Song, J. [1 ]
Ahmet, P. [1 ]
Kakushima, K. [2 ]
Tsutsui, K. [2 ]
Sugii, N. [2 ]
Hattori, T. [1 ]
Iwai, H. [1 ]
机构
[1] Tokyo Inst Technol, Frontier Res Ctr, Midori Ku, Yokohama, Kanagawa 2268502, Japan
[2] Tokyo Inst Technol, Interdisciplinary Grad Sch Sci & Engn, Midori Ku, Yokohama, Kanagawa 2268502, Japan
关键词
RAY PHOTOELECTRON-SPECTROSCOPY; GE; MOSFETS; SUBSTRATE; LAYER;
D O I
10.1088/0268-1242/25/6/065008
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
The feasibility of employing yttrium-scandium oxide (YScOx) as high-k gate dielectrics for germanium-metal-oxide-semiconductor (MOS) devices has been investigated. The composition and chemical structures of the film were studied using x-ray photoelectron spectroscopy (XPS). Conduction and valence band discontinuities at YScOx/Ge (100) interfaces were also determined by measuring the O 1s photoelectron energy loss and valence band spectra. Indeed, high-k (YScOx)/Ge MOS characteristics, exhibiting fairly good electrical characteristics, especially low leakage current density and low density of interface states, have been achieved due to the formation of stable Y-Sc-germanate at the interface. The effects of various scandium oxide (ScO) concentrations in YScOx on the electrical characteristics are also reported. It has been demonstrated that higher ScO concentration in YScOx may cause V-fb to shift to its even lower positive value even if considering hysteresis while it causes degradation in interfacial properties. Besides, the effects of several annealing treatments have been investigated in order to optimize the process conditions. This work suggests that ScO concentration up to 50% in YScOx along with post-metallization annealing treatment at 500 degrees C will be the key to ensure reasonable electrical performance of Ge MOS devices.
引用
收藏
页数:7
相关论文
共 31 条
[1]   Electrical Properties of Lanthanum-scandate Gate Dielectric Directly Deposited on Ge [J].
Bera, M. K. ;
Song, J. ;
Kakushima, K. ;
Ahmet, P. ;
Tsutsui, K. ;
Sugii, N. ;
Hattori, T. ;
Iwai, H. .
PHYSICS AND TECHNOLOGY OF HIGH-K GATE DIELECTRICS 7, 2009, 25 (06) :67-77
[2]  
CHOI CO, 2005, IEEE T ELECTRON DEV, V53, P1509
[3]   Dielectric and optical properties of epitaxial rare-earth scandate films and their crystallization behavior [J].
Christen, H. M. ;
Jellison, G. E., Jr. ;
Ohkubo, I. ;
Huang, S. ;
Reeves, M. E. ;
Cicerrella, E. ;
Freeouf, J. L. ;
Jia, Y. ;
Schlom, D. G. .
APPLIED PHYSICS LETTERS, 2006, 88 (26)
[4]   Scalability and electrical properties of germanium oxynitride MOS dielectrics [J].
Chui, CO ;
Ito, F ;
Saraswat, KC .
IEEE ELECTRON DEVICE LETTERS, 2004, 25 (09) :613-615
[5]   An X-ray photoelectron spectroscopy study of the HF etching of native oxides on Ge(111) and Ge(100) surfaces [J].
Deegan, T ;
Hughes, G .
APPLIED SURFACE SCIENCE, 1998, 123 :66-70
[6]   Interface engineering for Ge metal-oxide-semiconductor devices [J].
Dimoulas, A. ;
Brunco, D. P. ;
Ferrari, S. ;
Seo, J. W. ;
Panayiotatos, Y. ;
Sotiropoulos, A. ;
Conard, T. ;
Caymax, M. ;
Spiga, S. ;
Fanciulli, M. ;
Dieker, Ch. ;
Evangelou, E. K. ;
Galata, S. ;
Houssa, M. ;
Heyns, M. M. .
THIN SOLID FILMS, 2007, 515 (16) :6337-6343
[7]   Rare earth oxides as high-k dielectrics for Ge based MOS devices:: An electrical study of Pt/Gd2O3/Ge capacitors [J].
Evangelou, E. K. ;
Mavrou, G. ;
DimoulaS, A. ;
Konofaos, N. .
SOLID-STATE ELECTRONICS, 2007, 51 (01) :164-169
[8]   THE ROLE OF AN ULTRATHIN SILICON INTERLAYER AT THE SIO2-GE INTERFACE [J].
HATTANGADY, SV ;
MANTINI, MJ ;
FOUNTAIN, GG ;
RUDDER, RA ;
MARKUNAS, RJ .
JOURNAL OF APPLIED PHYSICS, 1992, 71 (08) :3842-3852
[9]   GATE-SELF-ALIGNED P-CHANNEL GERMANIUM MISFETS [J].
JACKSON, TN ;
RANSOM, CM ;
DEGELORMO, JF .
IEEE ELECTRON DEVICE LETTERS, 1991, 12 (11) :605-607
[10]  
Kamata Y, 2005, INT EL DEVICES MEET, P441