Frame transformation relations for fluxional symmetric rotor dimers

被引：6

作者：

Crogman, HT ^{[1
]}

Harter, WG ^{[1
]}

机构：

[1] Univ Arkansas, Dept Phys, Fayetteville, AR 72701 USA

来源：

JOURNAL OF CHEMICAL PHYSICS | 2004年 / 121卷 / 19期

关键词：

D O I：

10.1063/1.1786572

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The theory of frame transformation relation connecting body oriented angular momentum states and lab weakly coupled momentum states have been extended from rotor-electron to rotor-dimer systems. Coupling schemes are analyzed for weak and strong cases of correlation between lab and two different rotor body frames. It is shown that the frame transformation relation is a purely quantum effect at low angular momentum but an approach to a classical limit for high J. Symmetry analysis of frame transformation is compared to eigensolutions of model coupling Hamiltonian. (C) 2004 American Institute of Physics.

引用

页码：9297 / 9312

页数：16

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