Synthesis and electrical and optical properties of [PtTl2-xLix(C6F5)2(CCPh)2] (x=0, 1)

被引：51

作者：

Charmant, JPH

Forniés, J

Gómez, J

Lalinde, E

Merino, RI

Moreno, MT

Orpen, AG

机构：

[1] Univ Zaragoza, Inst Ciencia Mat Aragon, CSIC, E-50009 Zaragoza, Spain

[2] Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England

[3] Univ La Rioja, CSIC, UA, Dept Quim,Grp Sintesis Quim La Rioja, Logrono 26006, Spain

来源：

ORGANOMETALLICS | 2003年 / 22卷 / 04期

关键词：

D O I：

10.1021/om020972a

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis and properties of two novel platinum-thallium alkynyl complexes, [trans,cis,cis-PtTl2(C6F5)(2)(CdropCPh)(2)], 1 (X-ray), with two Tl(I)-Pt(II) bonds, and [cis-PtTlLi(C6F5)(2)-(CdropCPh)(2)], 2, which is an ionic conductor in the solid state, are presented. Both complexes exhibit a strong yellow luminescence, which is attributed, on the basis of TD-DFT calculations, to charge transfer from Tl-Pt-Tl (1) or Tl-Pt (2) units to the platinum metal fragments.

引用

页码：652 / 656

页数：5

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