Preparation of a chiral, 2-dimensional network containing metallacrown and copper benzoate building blocks

被引：104
作者：
Bodwin, JJ [1 ]
Pecoraro, VL [1 ]
机构：
[1] Univ Michigan, Dept Chem, Ann Arbor, MI 48109 USA
来源：
INORGANIC CHEMISTRY | 2000年 / 39卷 / 16期
关键词：
D O I：
10.1021/ic000562j
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Chiral metallacrowns have been fused into layers using neutral copper benzoate paddlewheel dimers and nitrate anions to link each 12-MC-4 molecule. The solid contains approximately 9 Angstrom channels that are filled with solvent and a benzoic acid guest. A related chain structure that is generated by connecting metallacrowns with the copper dimer, but which does not have nitrate bridges in the second dimension, also has channels of similar size. These observations suggest a generalizable strategy for the preparation of microporous chiral solids in bulk quantities. [GRAPHICS]
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页码：3434 / +
页数：3
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