Gamma-ray interaction with copper-doped bismuth-borate glasses

被引：108

作者：

ElBatal, F. H.

Marzouk, S. Y. ^{[1
]}

Nada, N.

Desouky, S. M.

机构：

[1] Natl Res Ctr, Electron Microscope & Thin Film Dept, Cairo, Egypt

[2] Natl Res Ctr, Glass Res Dept, Cairo, Egypt

[3] Ain Shams Univ, Dept Phys, Fac Girls, Cairo, Egypt

来源：

PHYSICA B-CONDENSED MATTER | 2007年 / 391卷 / 01期

关键词：

gamma ray; Raman spectra; infrared; UV spectroscopy; thermal expansion; copper-bismuth-borate glasses;

D O I：

10.1016/j.physb.2006.09.001

中图分类号：

O469 [凝聚态物理学];

学科分类号：

070205 ;

摘要：

Ultraviolet (UV)-visible, infrared (IR) and Raman spectroscoies together with thermal properties of Bi2O3-B2O3-CUO glasses were measured before and after gamma irradiation. It was shown that the UV-visible spectrum of the undoped Cu-free glass reveals before irradiation intense charge transfer UV bands due to the interference of trace iron impurities and Bi3+ while the visible spectrum shows no absorption bands. The CuO-doped glass reveals a broad visible band characteristic for Cu2+ ions. The absorption spectra of all the glasses show resistance to successive gamma irradiation. This shielding behavior is related to the high atomic mass of the metal ions (Bi3+). IR and Raman measurements reveal absorption bands which are characteristic for various groups of borate network and [BiO6] octahedra. (c) 2006 Elsevier B.V. All rights reserved.

引用

页码：88 / 97

页数：10

共 78 条

[61] Spectroscopic studies of transition metal doped sodium phosphate glasses [J].