Effect of anionic axial ligands on the formation of oxoiron(IV) porphyrin intermediates

被引:69
|
作者
Nam, W [1 ]
Lim, MH
Oh, SY
机构
[1] Ewha Womans Univ, Dept Chem, Seoul 120750, South Korea
[2] Ewha Womans Univ, Div Mol Life Sci, Seoul 120750, South Korea
关键词
D O I
10.1021/ic000502d
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Anionic axial ligands bound to an iron(III) porphyrin complex, Fe(TMP)X, showed a marked influence on the formation of oxoiron(IV) porphyrin intermediates in the reactions of PhIO and m-CPBA.
引用
收藏
页码:5572 / 5575
页数:4
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