Dielectric permittivity of kaolinite heated to high temperatures

被引:21
作者
Leluk, Karol [1 ]
Orzechowski, Kazimierz [1 ]
Jerie, Kazimierz [2 ]
Baranowski, Andrzej [2 ]
Slonka, Tadeusz [3 ]
Glowinski, Jozef [3 ]
机构
[1] Univ Wroclaw, Fac Chem, PL-50383 Wroclaw, Poland
[2] Univ Wroclaw, Inst Expt Phys, PL-50383 Wroclaw, Poland
[3] Wroclaw Univ Technol, Fac Chem, PL-50370 Wroclaw, Poland
关键词
Positron annihilation spectroscopy; Dielectric properties; ANNIHILATION; LIFETIME;
D O I
10.1016/j.jpcs.2010.02.008
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Heating of kaolinite from the room temperature to 600 degrees C results in a gradual decrease in the dielectric permittivity. However, when the temperature rises to 1000 degrees C the high frequency permittivity of kaolinite increases surprisingly. We suppose that the decomposition of the material produces imperfections, which liberate a small distance movement of polar groups. Positron annihilation experiments performed in this material confirm the appearance of empty volumes after kaolinite calcination. (C) 2010 Elsevier Ltd. All rights reserved.
引用
收藏
页码:827 / 831
页数:5
相关论文
共 24 条
[1]   HIGH DIELECTRIC-CONSTANT MICROWAVE PROBES FOR SENSING SOIL-MOISTURE [J].
BIRCHAK, JR ;
GARDNER, CG ;
HIPP, JE ;
VICTOR, JM .
PROCEEDINGS OF THE IEEE, 1974, 62 (01) :93-98
[3]   Adsorption of polyacrylamide on smectite, illite, and kaolinite [J].
Deng, YJ ;
Dixon, JB ;
White, GN .
SOIL SCIENCE SOCIETY OF AMERICA JOURNAL, 2006, 70 (01) :297-304
[4]   Positron annihilation studies in pyrophyllite [J].
Dryzek, J ;
Dryzek, E ;
Golonka, P .
JOURNAL OF PHYSICS-CONDENSED MATTER, 2002, 14 (50) :13857-13866
[5]   THE TEMPERATURE-DEPENDENCE OF POSITRON LIFETIMES IN SOLID PIVALIC ACID [J].
ELDRUP, M ;
LIGHTBODY, D ;
SHERWOOD, JN .
CHEMICAL PHYSICS, 1981, 63 (1-2) :51-58
[6]  
FICAI C, 1959, B SOC FR CERAM, V42, P7
[7]   Modification of the hydroxyl surface in potassium-acetate-intercalated kaolinite between 25 and 300 °C [J].
Frost, RL ;
Kristof, J ;
Mako, E ;
Kloprogge, JT .
LANGMUIR, 2000, 16 (19) :7421-7428
[8]   Void shapes and o-Ps lifetime in molecular crystals [J].
Jasinska, B ;
Koziol, AE ;
Goworek, T .
ACTA PHYSICA POLONICA A, 1999, 95 (04) :557-561
[9]   PROGRAM SYSTEM FOR ANALYZING POSITRON LIFETIME SPECTRA AND ANGULAR-CORRELATION CURVES [J].
KIRKEGAARD, P ;
ELDRUP, M ;
MOGENSEN, OE ;
PEDERSEN, NJ .
COMPUTER PHYSICS COMMUNICATIONS, 1981, 23 (03) :307-335
[10]   Reactivity of ionic liquids with kaolinite: Melt intersalation of ethyl pyridinium chloride in an urea-kaolinite pre-intercalate [J].
Letaief, Sadok ;
Elbokl, Tamer A. ;
Detellier, Christian .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2006, 302 (01) :254-258