Stereochemistry of radical polymerization of vinyl esters in the presence of Lewis acid

被引：15

作者：

Yamada, K

Nakano, T

Okamoto, Y

机构：

[1] Nagoya Univ, Grad Sch Engn, Dept Appl Chem, Chikusa Ku, Nagoya, Aichi 4648603, Japan

[2] Nagoya Univ, Grad Sch Engn, JCII, JRCPP,Chikusa Ku, Nagoya, Aichi 4648603, Japan

[3] Nara Inst Sci & Technol, Grad Sch Mat Sci, Nara 6300101, Japan

来源：

POLYMER JOURNAL | 2000年 / 32卷 / 08期

关键词：

vinyl ester; radical; polymerization; Lewis acid; aluminum tri-t-butoxide; tacticity; poly-(vinyl alcohol);

D O I：

10.1295/polymj.32.707

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The radical polymerization of vinyl esters was investigated in terms of stereochemistry in the presence of Lewis acid. Polymerization with stereocontrol was expected due to the interaction between the Lewis acid and the base. The syndiotacticity was based on the nature of the compound treated in the presence of Lewis acid.

引用

页码：707 / 710

页数：4

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