Unusual reactivities of N-heterocyclic carbenes upon coordination to the platinum(II)-dimethyl moiety

被引：45

作者：

Fortman, George C. ^{[3
]}

Scott, Natalie M. ^{[3
]}

Linden, Anthony ^{[1
]}

Stevens, Edwin D. ^{[2
]}

Dorta, Reto ^{[1
]}

Nolan, Steven P. ^{[2
,3
]}

机构：

[1] Univ Zurich, Inst Organ Chem, CH-8057 Zurich, Switzerland

[2] Univ New Orleans, Dept Chem, New Orleans, LA 70148 USA

[3] Univ St Andrews, EaStCHEM Sch Chem, St Andrews KY16 9ST, Fife, Scotland

来源：

CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 07期

关键词：

C-H ACTIVATION; REDUCTIVE ELIMINATION; COMPLEXES; LIGANDS; PLATINUM(IV); RUTHENIUM; KINETICS; METHANOL; SYSTEMS; BOND;

D O I：

10.1039/b920482b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Unsaturated NHCs of varying steric bulk undergo a series of unusual oxidative addition and reductive elimination processes upon binding to the Pt(Me)(2) fragment.

引用

页码：1050 / 1052

页数：3

共 30 条

[1] Coordinatively unsaturated hydridoruthenium(II) complexes of N-heterocyclic carbenes [J].

Abdur-Rashid, K ;

Fedorkiw, T ;

Lough, AJ ;

Morris, RH .

ORGANOMETALLICS, 2004, 23 (01) :86-94

[2] PREPARATIVE AND H-1-NMR SPECTROSCOPIC STUDIES ON PALLADIUM(II) AND PLATINUM(II) QUINOLINE-8-CARBALDEHYDE (1) COMPLEXES - X-RAY STRUCTURES OF THE CYCLOMETALATED ACYL COMPLEX PDCL(C(O)C9H6N)(PPH3).PPH3 AND TRANS-PTCL2(1)(PET3) [J].

ALBINATI, A ;

ANKLIN, CG ;

GANAZZOLI, F ;

RUEGG, H ;

PREGOSIN, PS .

INORGANIC CHEMISTRY, 1987, 26 (04) :503-508

[3] NJ(PT,H) AND PT-LESS-THAN-H-C INTERACTIONS IN SCHIFF-BASE COMPLEXES OF 2-(BENZYLIDENEAMINO)-3-METHYLPYRIDINE - MOLECULAR-STRUCTURES OF DICHLORO(2-((2,4,6-TRIMETHYLBENZYLIDENE)AMINO)-3-METHYLPYRIDINE)(TRIETHYLARSINE)PLATINUM(II) AND DICHLORO(2-AMINO-3-METHYLPYRIDINE)(TRIETHYLPHOSPHINE)PALLADIUM(II) [J].

ALBINATI, A ;

ARZ, C ;

PREGOSIN, PS .

INORGANIC CHEMISTRY, 1987, 26 (04) :508-513

[4] Reversible C-H bond activation reactions of the N-heterocyclic carbene ligands in Ru(Ph2PCH2CH2CH2PPh2)(IMes)(CO)H2 and Ru(Ph2AsCH2CH2PPh2)(IMes)(CO)H2 (IMes=1,3-dimesityl-1,3-dihydro-2H-imidazol-2-ylidene) [J].

Chilvers, MJ ;

Jazzar, RFR ;

Mahon, MF ;

Whittlesey, MK .

ADVANCED SYNTHESIS & CATALYSIS, 2003, 345 (9-10) :1111-1114

[5] Abnormal coordination of Arduengo's carbene upon reaction with M3(CO)12 (M=Ru, Os) [J].

Crittall, Matthew R. ;

Ellul, Charles E. ;

Mahon, Mary F. ;

Saker, Olly ;

Whittlesey, Michael K. .

DALTON TRANSACTIONS, 2008, (32) :4209-4211

[6] N-heterocyclic pincer dicarbene complexes of iron(II): C-2 and C-5 metalated carbenes on the same metal center [J].

Danopoulos, AA ;

Tsoureas, N ;

Wright, JA ;

Light, ME .

ORGANOMETALLICS, 2004, 23 (02) :166-168

[7] REDUCTIVE ELIMINATION OF A CARBON CARBON BOND FROM BIS(TRIALKYLPHOSPHINE)-3,3-DIMETHYLPLATINACYCLOBUTANES PRODUCES BIS(TRIALKYLPHOSPHINE)PLATINUM(0) AND 1,1-DIMETHYLCYCLOPROPANE [J].

DICOSIMO, R ;

WHITESIDES, GM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (13) :3601-3607

[8] N-Heterocyclic Carbenes in Late Transition Metal Catalysis [J].

Diez-Gonzalez, Silvia ;

Marion, Nicolas ;

Nolan, Steven P. .

CHEMICAL REVIEWS, 2009, 109 (08) :3612-3676

[9] Abnormally bound N-heterocyclic carbene complexes of ruthenium: C-H activation of both C4 and C5 positions in the same ligand [J].

Ellul, Charles E. ;

Mahon, Mary F. ;

Saker, Olly ;

Whittlesey, Michael K. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (33) :6343-6345

[10] Five-coordinate platinum(IV) complex as a precursor to a novel Pt(II) olefin hydride complex for alkane activation [J].

Fekl, U ;

Goldberg, KI .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (24) :6804-6805

← 1 2 3 →