Free hydrogen bonds in alcohol solutions with inert solvents

被引：17

作者：

Kanno, H ^{[1
]}

Honshoh, M ^{[1
]}

Yoshimura, Y ^{[1
]}

机构：

[1] Natl Def Acad, Dept Chem, Yokosuka, Kanagawa 2398686, Japan

来源：

JOURNAL OF SOLUTION CHEMISTRY | 2000年 / 29卷 / 10期

关键词：

Raman spectrum; free hydrogen bond; alcohol; inert solvent; solution;

D O I：

10.1023/A:1005142919076

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Raman spectra were obtained for alcohol solutions with inert solvents such as CCl4, CHCl3, etc. The frequency of the OH stretching vibrations [nu (OH)(free) band] due to free hydrogen bonds varies with change in either alcohol or inert solvent. It is shown that the frequency of the nu (OH)(free) band is sensitive to the shape of the head group of an inert solvent. The main cause for the frequency change of the nu (oH)(free) band with change in alcohol is ascribed to the change of effective mass of the vibrating unit (RO-H, R = alkyl group).

引用

页码：1007 / 1016

页数：10

共 25 条

[1] NUCLEAR MAGNETIC RESONANCE STUDIES OF HYDROGEN BONDING .2. ALCOHOLS [J].

DAVIS, JC ;

PITZER, KS ;

RAO, CNR .

JOURNAL OF PHYSICAL CHEMISTRY, 1960, 64 (11) :1744-1747

[2] MOLECULAR CONFORMERS IN GAS-PHASE ETHANOL - A TEMPERATURE STUDY OF VIBRATIONAL OVERTONES [J].

FANG, HL ;

SWOFFORD, RL .

CHEMICAL PHYSICS LETTERS, 1984, 105 (01) :5-11

[3] MOLECULAR STRUCTURE OF ETHANOL-D1 SOLUTIONS - NEAR-INFRARED STUDY OF HYDROGEN-BONDING [J].

FLETCHER, AN .

JOURNAL OF PHYSICAL CHEMISTRY, 1972, 76 (18) :2562-&

[4] SOLVATION OF CHLORIDE-IONS IN ALCOHOLS [J].

HONSHOH, M ;

KANNO, H ;

UEDA, T .

JOURNAL OF RAMAN SPECTROSCOPY, 1995, 26 (04) :289-293

[5]

HONSHOH M, UNPUB

[6] OPTIMIZED INTERMOLECULAR POTENTIAL FUNCTIONS FOR LIQUID ALCOHOLS [J].

JORGENSEN, WL .

JOURNAL OF PHYSICAL CHEMISTRY, 1986, 90 (07) :1276-1284

[7]

KANNO H, 1993, CRYO-LETT, V14, P115

[8] RAMAN SPECTRAL CHANGES OF ALCOHOLIC ZINC-CHLORIDE SOLUTIONS FROM LIQUID-STATE TO GLASSY STATE [J].

KANNO, H ;

YAMAUCHI, S .

JOURNAL OF SOLUTION CHEMISTRY, 1991, 20 (06) :589-594

[9] PRERESONANCE RAMAN EFFECT ON THE OD STRETCHING RAMAN-SPECTRA OF METHANOLIC LIX SOLUTIONS (X = CL, BR AND I) [J].

KANNO, H ;

YAMAUCHI, S .

JOURNAL OF RAMAN SPECTROSCOPY, 1993, 24 (07) :403-406

[10] A RAMAN-STUDY OF ALCOHOLIC LITHIUM PERCHLORATE SOLUTIONS IN THE GLASSY STATE [J].

KANNO, H ;

HONSHOH, M ;

YAMAUCHI, S .

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES, 1995, 50 (2-3) :257-262

← 1 2 3 →