Fundamentals, status and promise of sodium-based batteries

被引:929
作者
Usiskin, Robert [1 ]
Lu, Yaxiang [2 ]
Popovic, Jelena [1 ]
Law, Markas [3 ]
Balaya, Palani [3 ]
Hu, Yong-Sheng [2 ]
Maier, Joachim [1 ]
机构
[1] Max Planck Inst Solid State Res, Stuttgart, Germany
[2] Chinese Acad Sci, Inst Phys, Beijing Natl Lab Condensed Matter Phys, Key Lab Renewable Energy,Beijing Key Lab New Ener, Beijing, Peoples R China
[3] Natl Univ Singapore, Dept Mech Engn, Singapore, Singapore
关键词
CARBON-COATED NA3V2(PO4)(3); NA-ION BATTERY; LITHIUM-ION; ELECTROCHEMICAL PERFORMANCE; HIGH-CAPACITY; HARD CARBON; INSERTION ELECTRODES; LIQUID ELECTROLYTES; LATTICE ENERGIES; CATHODE MATERIAL;
D O I
10.1038/s41578-021-00324-w
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Na-based batteries have shown substantial progress in recent years and are promising candidates for mitigating the supply risks associated with Li-based batteries. In this Review, Na and Li batteries are compared in terms of fundamental principles and specific materials. Principles for the rational design of a Na battery architecture are discussed. Recent prototypes are surveyed to demonstrate that Na cells offer realistic alternatives that are competitive with some Li cells in terms of performance. Sodium batteries are promising candidates for mitigating the supply risks associated with lithium batteries. This Review compares the two technologies in terms of fundamental principles and specific materials, and assesses the performance of commercial prototype sodium cells.
引用
收藏
页码:1020 / 1035
页数:16
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