Diacridinium hexachloridoplatinate(IV) dihydrate

被引：3

作者：

Ha, Kwang ^{[1
]}

机构：

[1] Chonnam Natl Univ, Sch Appl Chem Engn, Res Inst Catalysis, Kwangju 500757, South Korea

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2010年 / 66卷

关键词：

D O I：

10.1107/S1600536810009566

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The asymmetric unit of the title compound, (C(13)H(10)N)(2)-[PtCl(6)]center dot 2H(2)O, contains a protonated acridine cation, one half of a [PtCl(6)](2-) dianionic complex and a solvent water molecule. The octahedral [PtCl(6)](2-) dianion is located on an inversion centre. pi-pi interactions between neighboring acridinium cations produce stacks along the a axis; the shortest distance between the centroids of the six- membered rings within the cations is 3.553 (9) angstrom. In the crystal, two independent intermolecular O-H center dot center dot center dot Cl hydrogen bonds, both involving the same Cl atom of the anion as acceptor, give rise to chains also running along the a axis; in addition each water molecule, as a hydrogen- bond acceptor, is linked to the acridinium N-H group.

引用

页码：M425 / U833

页数：10

共 9 条

[1]

Bruker, 2000, SAINT and SADABS

[2]

Farrugia L.J., 1997, J. Appl. Crystallogr., V30, P565, DOI [10.1107/S0021889897003117, DOI 10.1107/S0021889897003117]

[3] Studies on the structure and conduction mechanism of (Acrd)[Au(mnt)2]2.7 and (Phenz)[Au(mnt)2]3 molecular single crystals [J].